Controlled synthesis and growth mechanism of zinc cobalt sulfide rods on Ni-foam for high-performance supercapacitors

被引:85
作者
Hussain, Iftikhar [1 ]
Lamiel, Charmaine [1 ]
Mohameed, Saad Gomaa [1 ,2 ]
Vijayakumar, Subbukalai [1 ]
Ali, Awais [1 ]
Shim, Jae-Jin [1 ]
机构
[1] Yeungnam Univ, Sch Chem Engn, Gyongsan 38541, Gyeongbuk, South Korea
[2] TIMS, Min & Met Engn Dept, Helwan 109, Cairo 11421, Egypt
关键词
Zinc cobalt sulfide; Asymmetric supercapacitor; Growth mechanism; Energy density; Power density; REDUCED GRAPHENE OXIDE; NICKEL FOAM; NANOWIRE ARRAYS; ELECTROCHEMICAL PERFORMANCES; FACILE SYNTHESIS; ENERGY; ELECTRODE; COMPOSITE; STORAGE; NANOSTRUCTURES;
D O I
10.1016/j.jiec.2018.11.033
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Rod-like zinc cobalt sulfide (ZCS) with controlled uniform structure was synthesized using a single-step hydrothermal method and its growth mechanism was investigated. A ZCS-based electrode showed an ultrahigh capacitance of 2,418 F g(-1) (967 C g(-1)) at 1 A g(-1) with a good cycling stability of 83% after 10,000 cycles. Moreover, an asymmetric ZCS-12//activated carbon supercapacitor, exhibited a high capacitance of 142 F g(-1) (227 C g(-1)) at 0.5 A g(-1) and a high energy density of 51 Wh kg(-1) and a high power density of 8 kW kg(-1), highlighting the next generation high performance supercapacitors. (C) 2018 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.
引用
收藏
页码:250 / 259
页数:10
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