A minor isomer of C84 fullerene, D6h-C84(24), captured as a trifluoromethylated derivative, C84(CF3)12

被引：9
作者：
Tamm, Nadezhda B. [1 ]
Troyanov, Sergey I. [1 ]
机构：
[1] Moscow MV Lomonosov State Univ, Dept Chem, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2016年 / 26卷 / 04期
基金：
俄罗斯基础研究基金会;
关键词：
NMR-SPECTROSCOPY; IDENTIFICATION; PROOF;
D O I：
10.1016/j.mencom.2016.07.015
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An isomer of C-84 fullerene, D-3d-C-84(24)(CF3)(12), has been isolated by the HPLC method from the products of trifluoromethylation of C-84 fullerene mixture. Its molecular structure has been determined by a single crystal X-ray diffraction using synchrotron radiation. In the addition pattern, 12CF(3) groups are arranged as a loop of edge-sharing para-C-6(CF3)(2) hexagons. Isomer D-6h-C-84(24) has been identified in the form of a derivative for the first time.
引用
收藏
页码：312 / 313
页数：2
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