Sustainable utilization of lignocellulose: Preparation of furan derivatives from carbohydrate biomass by bifunctional lignosulfonate-based catalysts

被引：19

作者：

Chen, Dawei ^{[1
,2
]}

Liang, Fengbing ^{[1
]}

Feng, Dexin ^{[1
]}

Du, Fanglin ^{[2
]}

Zhao, Guang ^{[1
]}

Liu, Huizhou ^{[1
]}

Xian, Mo ^{[1
]}

机构：

[1] Chinese Acad Sci, Qingdao Inst Bioenergy & Bioproc Technol China, CAS Key Lab Biobased Mat, Beijing 100864, Peoples R China

[2] Qingdao Univ Sci & Technol, Coll Mat Sci & Engn, Key Lab Nanostruct Mat, Qingdao 266042, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2016年 / 84卷

关键词：

Lignocellulose; Cellulose; Xylan; HMF; Furfural; IONIC LIQUIDS; ACID; CONVERSION; LIGNIN; ISOMERIZATION; CHEMICALS; FRUCTOSE; GLUCOSE; XYLOSE; WATER;

D O I：

10.1016/j.catcom.2016.06.012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Bifunctional lignosulfonate-based catalysts (LS-M) with Lewis acid and basic sites were designed and prepared by immobilizing metal ions on lignosulfonate. Catalysts were characterized by XRD, XPS, SEM, EDX, TEM, TGA, NH3/CO2-TPD and FTIR, and applied in transformation of carbohydrate biomass to furan derivatives (HMF/furfural) in mixed water/THF systems. With LS-Cr as catalyst, the optimized yields of HMF from cellulose, glucose and mannose were 46.3%, 60.4% and 68.8%, and that of furfural from xylan, xylose and arabinose were 40.2%, 73.1% and 51.6%, respectively. The catalysts could be easily recycled with negligible wastage of the active metal ions. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：159 / 162

页数：4

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