Functionalized twistacenes for solid state nonlinear optical materials

被引：15

作者：

Zhai, Guixia ^{[1
]}

Li, Xinyue ^{[2
]}

Jin, Pengcheng ^{[1
]}

Semin, Sergey ^{[3
]}

Xiao, Jinchong ^{[1
]}

Rasing, Theo ^{[3
]}

Xu, Jialiang ^{[2
]}

机构：

[1] Hebei Univ, Coll Chem & Environm Sci, Key Lab Chem Biol Hebei Prov, Baoding 071002, Peoples R China

[2] Tianjin Univ, Sch Chem Engn & Technol, Yaguan Rd 135, Tianjin 300350, Peoples R China

[3] Radboud Univ Nijmegen, Inst Mol & Mat, Heyendaalseweq 135, NL-6525 AJ Nijmegen, Netherlands

来源：

DYES AND PIGMENTS | 2018年 / 149卷

基金：

中国国家自然科学基金;

关键词：

Twisted structure; Single crystal; Acene; Physical property; Nonlinear optical response; LIGHT-EMITTING-DIODES; FUSED BENZENE RINGS; PHYSICAL-PROPERTIES; TWISTED ACENES; DERIVATIVES; BEHAVIOR; HETEROTWISTACENES; ARCHITECTURES; AZAACENES; RESPONSES;

D O I：

10.1016/j.dyepig.2017.12.009

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

A series of twistacenes with different substituents have been synthesized, characterized, and their nonlinear optical properties in the solid state have been explored. It is demonstrated that 2,7-di-tert-butyl-N,9,20-triphenyltetrabenzo[a,cjk,op]pentacen-11-amine crystals having a centrosymmetric C-2/c space group exhibit third order and strong second-order nonlinear optical responses with well-defined polarization dependencies.

引用

页码：876 / 881

页数：6

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