Reactions of Ru-3(mu-dppm)(CO)(1)0 with unsaturated hydrocarbons. Pentamethylcyclopentadiene. X-ray structure of Ru-4(mu-H)(mu(3)-PPhCH(2)PPh(2))(mu-eta(1):eta(5)-CH(2)C(5)Me(4))(CO)(8)

被引:8
作者
Bruce, MI [1 ]
Humphrey, PA [1 ]
Skelton, BW [1 ]
White, AH [1 ]
机构
[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA
基金
澳大利亚研究理事会;
关键词
ruthenium; cluster; crystal structure; pentamethylcyclopentadiene;
D O I
10.1016/0022-328X(96)06256-0
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Reactions between Ru-3(mu-dppm)(CO)(10) and pentamethylcyclopentadiene in refluxing THF afford Ru-4(mu-H)(mu(3)-PPhCH(2)PPh(2))(mu-eta(1) :eta(5)-CH(2)C(5)Me(4))(CO)(8) as the major isolable product. The cluster contains a tetrahedral Ru-4 core, one face of which is capped by the mu(3)-PPhCH(2)PPh(2) ligand, with edges bridged by an H atom, two CO groups and a mu-eta(1):eta(5)-CH(2)C(5)Me(4) ligand.
引用
收藏
页码:259 / 263
页数:5
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