Reactions of Ru-3(mu-dppm)(CO)(1)0 with unsaturated hydrocarbons. Pentamethylcyclopentadiene. X-ray structure of Ru-4(mu-H)(mu(3)-PPhCH(2)PPh(2))(mu-eta(1):eta(5)-CH(2)C(5)Me(4))(CO)(8)

被引：8

作者：

Bruce, MI ^{[1
]}

Humphrey, PA ^{[1
]}

Skelton, BW ^{[1
]}

White, AH ^{[1
]}

机构：

[1] UNIV WESTERN AUSTRALIA,DEPT CHEM,NEDLANDS,WA 6907,AUSTRALIA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1996年 / 522卷 / 02期

基金：

澳大利亚研究理事会;

关键词：

ruthenium; cluster; crystal structure; pentamethylcyclopentadiene;

D O I：

10.1016/0022-328X(96)06256-0

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Reactions between Ru-3(mu-dppm)(CO)(10) and pentamethylcyclopentadiene in refluxing THF afford Ru-4(mu-H)(mu(3)-PPhCH(2)PPh(2))(mu-eta(1) :eta(5)-CH(2)C(5)Me(4))(CO)(8) as the major isolable product. The cluster contains a tetrahedral Ru-4 core, one face of which is capped by the mu(3)-PPhCH(2)PPh(2) ligand, with edges bridged by an H atom, two CO groups and a mu-eta(1):eta(5)-CH(2)C(5)Me(4) ligand.

引用

页码：259 / 263

页数：5

共 18 条

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