Synthesis and crystal structure of [Cu(HIm)2(PPh3)2] (BF4)

被引：0

作者：

Li, D ^{[1
]}

Li, RZ

Qi, ZY

Xu, YP

Feng, XL

Cai, JW

机构：

[1] Shantou Univ, Dept Chem, Shantou 515063, Peoples R China

[2] Zhongshan Univ, Instrumentat Anal & Res Ctr, Guangzhou 510275, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2001年 / 17卷 / 04期

关键词：

copper(I) complex; imidazole; triphenylphosphine; crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A Cu (I) complex with mix-ligands [Cu(HIm)(2)(PPh3)(2)] (BF4) was synthesized and characterized by elemental analysis, IR spectroscopy and X-ray diffraction crystallography. The crystal belongs to monoclinic system and P2(1)/c space group, with cell parameters, a = 1.2836(3)nm, b = 1.5089(3) nm, c=2.0661(4) nm, alpha =90 degrees, beta =101.464(4)degrees, gamma =90 degrees, V=3.9219(13) nm(3), Z=4 and D-c = 1,374mg (.) m(-3). The Cu (I) is coordinated by two P atoms from triphenylphosphine and two N atoms from imidazole to form the distorted tetrahedral geometry.

引用

页码：593 / 596

页数：4

共 12 条

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