Novel materials for solid oxide fuel cell technologies: A literature review

被引:314
作者
da Silva, Fellipe Sartori [1 ]
de Souza, Teofilo Miguel [1 ]
机构
[1] Sao Paulo State Univ Unesp, Sch Engn, Ariberto Pereira Cunha Ave 333, BR-12516410 Guaratingueta, Brazil
关键词
Solid oxide fuel cell; Anode; Cathode; Electrolyte; Materials; GAS-SHIFT REACTION; WATER STORAGE CAPABILITY; CATHODE MATERIALS; COMPOSITE CATHODE; DOUBLE-PEROVSKITE; ELECTROCHEMICAL PROPERTIES; IONIC-CONDUCTIVITY; PROTON CONDUCTION; SULFUR TOLERANCE; HIGH-TEMPERATURE;
D O I
10.1016/j.ijhydene.2017.08.105
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
This study aims to review novel materials for solid oxide fuel cell (SOFC) applications covered in literature. Thence, it was found that current SOFC operating conditions lead to issues, such as carbon surface deposition, sulfur poisoning and quick component degradation at high temperatures, which make it unsuitable for a few applications. Therefore, many researches are focused on cell performance enhancement through replacing the materials being used in order to improve properties and/or reduce operating temperatures. Most modifications in the anode aim to avoid some issues concerning conventionally used Ni-based materials, such as carbon deposition and sulfur poisoning, besides enhancing catalytic activity, once this component is directly exposed to the fuel. It was also found literature about the cathode with the aim of developing a material with enhanced properties in a wider temperature range, which has been compared to the currently used one: LSM perovsldte (La1-xSrxMnO3). Novel electrolyte materials can have ionic or protonic conductivity, thus performance degradation must be avoided at several operating conditions. In order to enhance its electrochemical performance, different materials for electrodes (cathode and anode) and electrolytes have been assessed herein. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:26020 / 26036
页数:17
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