Electropolymerization of Polypyrrole and Polypyrrole-ZnO Nanocomposites on Mild Steel and Its Corrosion Protection Performance

被引：66

作者：

Hosseini, M. G. ^{[1
]}

Bagheri, R. ^{[1
]}

Najjar, R. ^{[2
]}

机构：

[1] Univ Tabriz, Dept Phys Chem, Electrochem Res Lab, Tabriz, Iran

[2] Univ Tabriz, Dept Organ Chem, Polymer Res Lab, Tabriz, Iran

来源：

JOURNAL OF APPLIED POLYMER SCIENCE | 2011年 / 121卷 / 06期

关键词：

conducting polymers; nanocomposites; electrochemistry; corrosion; polypyrrole; CONDUCTING POLYMER-COATINGS; TUNGSTATE ION DOPANTS; STAINLESS-STEEL; COMPOSITES; PHOSPHATE;

D O I：

10.1002/app.33952

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Polypyrrole (PPy) and Polypyrrole-ZnO (PPy-ZnO) nanocomposites were electrodeposited on mild steel and its corrosion protection ability was studied by Tafel and Impedance techniques in 3.5% NaCl solution. Pure Polypyrrole film was not found to protect the mild steel perfectly but the coating with nano-sized ZnO (PPy-ZnO) has dramatically increased the corrosion resistance of mild steel. Electrochemical Impedance Spectroscopy (EIS) measurements indicated that the coating resistance (R(coat)) and corrosion resistance (R(corr)) values for the PPy-ZnO nanocomposite coating was much higher than that of pure PPy coated electrode. (C) 2011 Wiley Periodicals, Inc. J Appl Polym Sci 121: 3159-3166,

引用

页码：3159 / 3166

页数：8

共 30 条

[1]

Anuar K., 2004, MAT SCI, V10, P255

[2]

Armes S., 1998, HDB CONDUCTING POLYM, P423

[3] Morphological investigations of polypyrrole coatings on stainless steel [J].

Ashrafi, A. ;

Golozar, M. A. ;

Mallakpour, S. .

SYNTHETIC METALS, 2006, 156 (18-20) :1280-1285

[4] Synthesis and interfacial properties of montmorillonite/polypyrrole nanocomposites [J].

Boukerma, K ;

Piquemal, JY ;

Chehimi, MM ;

Mravcáková, M ;

Omastová, M ;

Beaunier, P .

POLYMER, 2006, 47 (02) :569-576

[5] Polypyrrole/polyphosphate organic-inorganic nanocomposites [J].

Castro, EG ;

Zarbin, AJG ;

Galembeck, A .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2005, 351 (49-51) :3704-3708

[6] Synthesis and characterization of polypyrrole/TiO2 composites on mild steel [J].

Ferreira, CA ;

Domenech, SC ;

Lacaze, PC .

JOURNAL OF APPLIED ELECTROCHEMISTRY, 2001, 31 (01) :49-56

[7] Surface modification of zinc oxide nanoparticles by aminopropyltriethoxysilane [J].

Grasset, F ;

Saito, N ;

Li, D ;

Park, D ;

Sakaguchi, I ;

Ohashi, N ;

Haneda, H ;

Roisnel, T ;

Mornet, S ;

Duguet, E .

JOURNAL OF ALLOYS AND COMPOUNDS, 2003, 360 (1-2) :298-311

[8] Kinetics of the mild steel corrosion protection by polypyrrole-oxalate coating in sulfuric acid solution [J].

Grgur, Branimir N. ;

Zivkovic, Predrag ;

Gvozdenovic, Milica M. .

PROGRESS IN ORGANIC COATINGS, 2006, 56 (2-3) :240-247

[9] Corrosion protection of iron by polypyrrole modified by copper using the cementation process [J].

Hammache, H ;

Makhloufi, L ;

Saidani, B .

CORROSION SCIENCE, 2003, 45 (09) :2031-2042

[10] Comparison of the Corrosion Protection of Mild Steel by Polypyrrole-Phosphate and Polypyrrole-Tungstenate Coatings [J].

Hosseini, M. G. ;

Sabouri, M. ;

Shahrabi, T. .

JOURNAL OF APPLIED POLYMER SCIENCE, 2008, 110 (05) :2733-2741

← 1 2 3 →