Review of one-dimensional and two-dimensional nanostructured materials for hydrogen generation

被引:145
作者
Babu, Veluru Jagadeesh [1 ]
Vempati, Sesha [1 ]
Uyar, Tamer [1 ,2 ]
Ramakrishna, Seeram [3 ]
机构
[1] Bilkent Univ, UNAM, Natl Nanotechnol Res Ctr, TR-06800 Ankara, Turkey
[2] Bilkent Univ, Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey
[3] Natl Univ Singapore, NUSNNI, NUSCNN, Singapore 117576, Singapore
关键词
TIO2 NANOTUBE ARRAYS; ENHANCED PHOTOCATALYTIC ACTIVITY; SENSITIZED SOLAR-CELLS; CORE-SHELL NANORODS; TITANIUM-DIOXIDE NANOMATERIALS; LOW-TEMPERATURE SYNTHESIS; GRAPHITIC CARBON NITRIDE; VISIBLE-LIGHT; NANOWIRE ARRAYS; ELECTROSPUN NANOFIBERS;
D O I
10.1039/c4cp04245j
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Hydrogen is an attractive alternative to fossil fuels in terms of environmental and other advantages. Of the various production methods for H-2, photocatalysis requires further development so that it can be applied economically on an industrial scale. One- and two-dimensional nanostructures in both pristine and modified forms have shown great potential as catalysts in the generation of H-2. We review here recent developments in these nanostructure catalysts and their efficiency in the generation of H-2 under UV/visible/simulated solar light. Despite much research effort, many photocatalysts do not yet meet the practical requirements for the generation of H-2, such as visible light activity. H-2 production is dependent on a variety of parameters and factors. To meet future energy demands, several challenges in H-2 production still need to be solved. We address here the factors that influence the efficiency of H-2 production and suggest alternatives. The nanostructures are classified based on their morphology and their efficiency is considered with respect to the influencing parameters. We suggest effective ways of engineering catalyst combinations to overcome the current performance barriers.
引用
收藏
页码:2960 / 2986
页数:27
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