Sterically crowded monomeric neutral bis(benzamidinato) compounds of aluminium, [PhC(NSiMe(3))(2)](2)AlX (X=Cl, H); X-ray crystal structure of [PhC(NSiMe(3))(2)]2AlH

被引：40

作者：

Duchateau, R ^{[1
]}

Meetsma, A ^{[1
]}

Teuben, JH ^{[1
]}

机构：

[1] UNIV GRONINGEN,CTR CATALYSIS & SYNTH,DEPT CHEM,9747 AG GRONINGEN,NETHERLANDS

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000223

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

AlCl3 reacts with [PhC(NSiMe(3))(2)]Li(OEt(2)) to afford the bis(N,N'-bis(trimethylsilyl)benzamidinato)aluminium chloro compound which, on treatment with KBEt(3)H, yields the structurally characterized monomeric hydride derivative, [PhC(NSiMe(3))(2)]2AlH, whose reactivity towards unsaturated hydrocarbons illustrates the low electrophilicity of the aluminium and high basic character of the hydride group.

引用

页码：223 / 224

页数：2

共 20 条

[1] POLYDENTATE TERTIARY AMINE ALUMINUM-HYDRIDE ADDUCTS - MONOMERIC VERSUS POLYMERIC SPECIES
ATWOOD, JL
BENNETT, FR
JONES, C
KOUTSANTONIS, GA
RASTON, CL
ROBINSON, KD
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1992, (07) : 541 - 543
[2] N,N'-DI-TERT-BUTYLETHYLENEDIAMINE-CLNH3-NALNME(3) DERIVATIVES - ALANE-RICH [(H2AL)(2)(MU-N(BU(T))CH2)2] AND STABLE, INTRAMOLECULAR SECONDARY AMINE ALANE COMPLEXES [CLNH2-NAL( N(H)(BU(T))CH(2)CH(2)NBU(T)], N=0,1
ATWOOD, JL
LAWRENCE, SM
RASTON, CL
[J]. JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (01) : 73 - 74
[3] TRANSITION-METAL ALUMINOHYDRIDE COMPLEXES
BARRON, AR
WILKINSON, G
[J]. POLYHEDRON, 1986, 5 (12) : 1897 - 1915
[4] LASER-INDUCED CHEMICAL VAPOR-DEPOSITION OF ALUMINUM
BAUM, TH
LARSON, CE
JACKSON, RL
[J]. APPLIED PHYSICS LETTERS, 1989, 55 (12) : 1264 - 1266
[5] STABLE TERTIARY PHOSPHINE ADDUCTS OF ALANE
BENNETT, FR
ELMS, FM
GARDINER, MG
KOUTSANTONIS, GA
RASTON, CL
ROBERTS, NK
[J]. ORGANOMETALLICS, 1992, 11 (04) : 1457 - 1459
[6] A NEW STAGE IN THE DEVELOPMENT OF TRANSITION-METAL ALUMOHYDRIDES
BULYCHEV, BM
[J]. POLYHEDRON, 1990, 9 (2-3) : 387 - 408
[7] DUCHATEAU R, UNPUB ORGANOMETALLIC
[8] PREPARATION OF NEW LITHIUM ORGANOTRIHYDROALUMINATES - CRYSTAL-STRUCTURE OF ((C4H8O)(2)LI(MU-H)(2)ALH[C(SIME(2)PH)(3)])(2)
EABORN, C
GORRELL, IB
HITCHCOCK, PB
SMITH, JD
TAVAKKOLI, K
[J]. ORGANOMETALLICS, 1994, 13 (11) : 4143 - 4144
[9] EISCH JJ, 1982, COMPREHENSIVE ORGANO, V1, P555
[10] THE CRYSTAL-STRUCTURE OF N,N,N'-TRIS(TRIMETHYLSILYL)BENZAMIDINE, AS WELL AS THE SYNTHESIS AND CRYSTAL-STRUCTURE OF DICHLOROANTIMONY-N,N'-BIS(TRIMETHYLSILYL)BENZAMIDINATE
ERGEZINGER, C
WELLER, F
DEHNICKE, K
[J]. ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1988, 43 (09): : 1119 - 1124

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