Resolution of chiral polyoxoanion[P2Mo18O62]6- with histidine

被引：37
|
作者：
Liu, Ding [1 ]
Tan, Hua-Qiao [1 ]
Chen, Wei-Lin [1 ]
Li, Yang-Guang [1 ]
Wang, En-Bo [1 ]
机构：
[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China
来源：
CRYSTENGCOMM | 2010年 / 12卷 / 07期
基金：
中国国家自然科学基金;
关键词：
AQUEOUS ALKALINE-SOLUTION; POLYOXOMETALATE CLUSTERS; CRYSTAL-STRUCTURE; 3D ARCHITECTURES; NMR-SPECTROSCOPY; BUILDING-BLOCKS; AMINO-ACIDS; ANIONS; FRAMEWORK;
D O I：
10.1039/c001160f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The classical Dawson-type racemic polyoxoanions [P2Mo18O62](6-) have been separated in aqueous solution with L,D-histidine, respectively. Two enantiomerically pure compounds: H-3(L-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1a), H-3(D-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1b), have been synthesized.
引用
收藏
页码：2044 / 2046
页数：3
相关论文
共 50 条
  • [21] STABILIZATION AND MAGNETIC-RESONANCE CHARACTERIZATION OF THE ONE-ELECTRON HETEROPOLY BLUE DERIVATIVE OF THE MOLYBDOPHOSPHATE [P2MO18O62](6-) - SLOW INTRAMOLECULAR PROTON-EXCHANGE OF THE 2-ELECTRON BLUE IN ACETONITRILE SOLUTION
    BARROWS, JN
    POPE, MT
    INORGANICA CHIMICA ACTA, 1993, 213 (1-2) : 91 - 98
  • [22] Selective determination of ascorbic acid with a novel hybrid material based 1-butyl-3-methylimidazolium tetrafluoroborate ionic liquid and the Dawson type ion [P2Mo18O62]6- immobilized on glassy carbon
    Ammam, Malika
    Easton, E. Bradley
    ELECTROCHIMICA ACTA, 2011, 56 (07) : 2847 - 2855
  • [23] Two new inorganic-organic hybrid materials based on inorganic cluster, [X2Mo18O62]6- (X=P, As)
    Hmida, Fatma
    Ayed, Meriem
    Ayed, Brahim
    Haddad, Amor
    JOURNAL OF CHEMICAL SCIENCES, 2015, 127 (09) : 1645 - 1651
  • [24] Polyoxometalate K6[P2Mo18O62] Inactivates Escherichia coli O157:H7 by Inducing recA Expression and Apoptosis-like Bacterial Death
    Lin, Shaoling
    Lin, Zhongjing
    Zhou, Feng
    Wang, Dehua
    Zheng, Baodong
    Hu, Jiamiao
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2023, 24 (14)
  • [25] 超分子化合物[C6H11NH3]6[P2Mo18O62]·4H2O的水热法合成及结构
    王敬平
    王子梁
    牛景杨
    应用化学, 2004, (01) : 45 - 48
  • [26] Self-assembly of four functional coordination polymers based on α-{P2W18O62}6-
    Luo, Yu-Hui
    Li, Bo
    Yu, Xiao-Yang
    Han, Chao-Ming
    Lu, Xin-Xin
    Zhang, Hong
    Chen, Xin
    POLYHEDRON, 2015, 85 : 705 - 711
  • [27] Study on the Regulation and Mechanism of the Vanadium Substituted Polyoxometalates of H8[P2Mo18O62] on Melanogenesis of Mouse Melanoma Cell B16
    Chen Xiangsong
    Shuai Die
    Jiang Zedong
    Yang Han
    Luo Dan
    Ni Hui
    Wang Li
    Chen Bingnian
    ACTA CHIMICA SINICA, 2022, 80 (02) : 116 - 125
  • [28] Coupled electron- and proton transfer processes in the reduction of α-[P2W18O62]6- and α-[H2W12O40]6- as revealed by simulation of cyclic voltammograms
    Prenzler, PD
    Boskovic, C
    Bond, AM
    Wedd, AG
    ANALYTICAL CHEMISTRY, 1999, 71 (17) : 3650 - 3656
  • [29] Vanadium(V)-Substitution Reactions of Wells-Dawson-Type Polyoxometalates: From [X2M18O62](6-) (X = P, As; M = Mo, W) to [X2VM17O62](7-)
    Ueda, Tadaharu
    Nishimoto, Yuriko
    Saito, Rie
    Ohnishi, Miho
    Nambu, Jun-ichi
    INORGANICS, 2015, 3 (03) : 355 - 369
  • [30] Fast Microwave-Assisted Synthesis of Wells-Dawson-Type 18-Tungsto-2-Phosphate [P2W18O62]6-
    Pandya, Vamangi M.
    Haider, Ali
    Qasim, Hafiz M.
    Mougharbel, Ali S.
    Kortz, Ulrich
    Joshi, Sachin A.
    INORGANICS, 2019, 7 (02)
12345