Resolution of chiral polyoxoanion[P2Mo18O62]6- with histidine

被引：37

作者：

Liu, Ding ^{[1
]}

Tan, Hua-Qiao ^{[1
]}

Chen, Wei-Lin ^{[1
]}

Li, Yang-Guang ^{[1
]}

Wang, En-Bo ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Minist Educ, Key Lab Polyoxometalate Sci, Changchun 130024, Jilin, Peoples R China

来源：

CRYSTENGCOMM | 2010年 / 12卷 / 07期

基金：

中国国家自然科学基金;

关键词：

AQUEOUS ALKALINE-SOLUTION; POLYOXOMETALATE CLUSTERS; CRYSTAL-STRUCTURE; 3D ARCHITECTURES; NMR-SPECTROSCOPY; BUILDING-BLOCKS; AMINO-ACIDS; ANIONS; FRAMEWORK;

D O I：

10.1039/c001160f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The classical Dawson-type racemic polyoxoanions [P2Mo18O62](6-) have been separated in aqueous solution with L,D-histidine, respectively. Two enantiomerically pure compounds: H-3(L-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1a), H-3(D-HC6H9N3O2)(3)[P2Mo18O62]center dot 20H(2)O (1b), have been synthesized.

引用

页码：2044 / 2046

页数：3

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