Study on the flame-retarding mechanism of brominated polystyrene waste in cured epoxy resin

被引：2

作者：

Xiao, WD ^{[1
]}

He, PX ^{[1
]}

He, BQ ^{[1
]}

Zhang, FM ^{[1
]}

机构：

[1] Hubei Univ, Wuhan 430062, Peoples R China

来源：

JOURNAL OF FIRE SCIENCES | 2003年 / 21卷 / 04期

关键词：

thermal analysis; limiting oxygen index determination; bromopolystyrene waste; pyrolysis kinetics; flame-retardation; epoxy resin;

D O I：

10.1177/0734904103021004006

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Limiting oxygen index determination and TG methods results illustrate that the bromopolystyrene produced can flame-retard cured epoxy resin effectively by gas phase and condensed phase mechanisms. The results of thermal analysis (TG and DSC) and direct heating in air show that BPS loses bromine atoms mainly at 310-420degreesC at a high rate. The pyrolysis kinetics parameter n is zero, E is 209.8 kJ/mol and A is 2.6 x 10(17), the rate constant and half-life also have been obtained. It is very stable below 200degreesC in air and is durable in use. The kinetics equation has larger practical value than the TG curves themselves.

引用

页码：319 / 329

页数：11