Syntheses and solid state structures of hybrid d10 metal-organic frameworks based on methylenediisophthalic acid (H4MDIP)

被引：48

作者：

Duan, Xianying ^{[1
]}

Li, Yizhi ^{[1
]}

Su, Yang ^{[1
]}

Zang, Shuangquan ^{[1
]}

Zhu, Chengjian ^{[1
]}

Meng, Qingjin ^{[1
]}

机构：

[1] Nanjing Univ, Inst Coordinat Chem, State Key Lab Coordinat Chem, Sch Chem & Chem Engn, Nanjing 210008, Peoples R China

来源：

CRYSTENGCOMM | 2007年 / 9卷 / 09期

关键词：

D O I：

10.1039/b618613k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Four novel hybrid d(10) metal complexes [Zn( H2MDIP)(4,4'- bpy) (0.5)](n) 1 (4,4'- bpy = 4,4'- bipyridine, H4MDIP = methylenediisophthalic acid), [ Zn-2( MDIP)( bix)center dot H2O](n) 2 [ bix = 1,4-bis( imidazol-1-ylmethyl)- benzene], {[Cd( H2MDIP)( H2O)] (2)center dot H2O}(n) 3, {[Cd-2( MDIP)( H2O)(2)(en)(2)]center dot 2H(2)O}(n) 4 ( en 5 ethylenediamine) based on tetracarboxylate acid were synthesized and their structures were determined by X-ray single-crystal diffraction. Complexes 1 - 2 are 2D grid and undulated structures with four-coordinated Zn2+ ions, respectively; 3 - 4 are 2D grid and double-sheet structures with six-coordinated Cd2+ ions, respectively. MDIP in complexes 1 and 3 act as V-shaped and Y-shaped ligands, respectively, yet in 2 and 4 MDIP act as similar X-shaped ligands. Diverse topologies, thermal and luminescent properties of complexes 1 - 4 have also been investigated.

引用

页码：758 / 766

页数：9

共 37 条

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