Synthesis and thermal properties for 4-(4-alkoxyphenoxycarbonyl)phenyl 3-alkoxy-2-X-benzoates

被引:3
|
作者
Okamoto, H [1 ]
Morita, Y [1 ]
Segawa, Y [1 ]
Takenaka, S [1 ]
机构
[1] Yamaguchi Univ, Fac Engn, Dept Adv Mat Sci & Engn, Ube, Yamaguchi 7558611, Japan
关键词
binary phase diagram; lateral substituent; liquid crystals; nematic phase; synthesis;
D O I
10.1080/15421400590957071
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Some derivatives of 4-(4-alkoxyphenoxycarbonyl)phenyl 3-alkoxy-2-X-benzoates (X=F, Cl, Br, or CF3) were synthesized by means of an ortho-directed lithiation followed by an electrophilic aromatic substitution reaction, as a key step, and their thermal properties of liquid crystals were examined. These results are discussed in terms of molecular structure and electrostatic effects.
引用
收藏
页码:2087 / 2093
页数:7
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