Modular Approach for Synthesis of Vicinal Diamines Containing Axial Chiral 1,1′-Binaphthyl from 1,2-Diaminoethane by Pd-Catalyzed N-Arylation Reactions

被引：12

作者：

Zhu, Shifa ^{[1
,2
]}

Wang, Chao ^{[1
]}

Chen, Lijuan ^{[1
]}

Liang, Renxiao ^{[1
]}

Yu, Yingfeng ^{[1
]}

Jiangt, Huanfeng ^{[1
]}

机构：

[1] S China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China

[2] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China

来源：

ORGANIC LETTERS | 2011年 / 13卷 / 05期

基金：

中央高校基本科研业务费专项资金资助; 中国国家自然科学基金;

关键词：

OLEFIN METATHESIS; CONJUGATED DIENES; DIAMINATION; COMPLEXES; ALKENES; LIGANDS; BINOL;

D O I：

10.1021/ol103169z

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A very convenient and efficient modular approach for the synthesis of vicinal diamines containing axial chiral 1,1'-binaphthyl from 1,2-diaminoethane by Pd-catalyzed N-arylation reactions has been developed. The resulting chiral diamines could be easily converted into NHC precursors, imidazole salts, in good yields.

引用

页码：1146 / 1149

页数：4

共 23 条

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