Increased selectivity in hydroformylation reactions using dendrimer based catalysts; a positive dendrimer effect

被引：119
作者：
Ropartz, L [1 ]
Morris, RE [1 ]
Foster, DF [1 ]
Cole-Hamilton, DJ [1 ]
机构：
[1] Univ St Andrews, Sch Chem, CATS, St Andrews KY16 9ST, Fife, Scotland
来源：
CHEMICAL COMMUNICATIONS | 2001年 / 04期
关键词：
D O I：
10.1039/b009574p
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Dendrimers based on polyhedral oligomeric silsesquioxanes (POSS) cores with 16 PPh2 arms give much higher linear selectivities (14:1) than their small molecule analogues (3-4:1) in the hydroformylation of oct-1-ene.
引用
收藏
页码：361 / 362
页数：2
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