Characterization process to measure the electrical contact resistance of Gas Diffusion Layers under mechanical static compressive loads

被引:39
作者
El Oualid, S. [1 ,2 ,3 ]
Lachat, R. [2 ,4 ]
Candusso, D. [3 ,5 ]
Meyer, Y. [1 ,2 ]
机构
[1] Univ Bourgogne Franche Comte, UTBM, Belfort, France
[2] Univ Bourgogne Franche Comte, UTBM, FCellSys, Belfort, France
[3] UTBM, FCLAB, FR CNRS 3539, Batiment F,Rue Thierry Mieg, F-90010 Belfort, France
[4] Univ Bourgogne Franche Comte, UTBM, CNRS, ICB UMR 6303, Belfort, France
[5] IFSTTAR COSYS SATIE UMR CNRS 8029, 25 Allee Marronniers, F-78000 Versailles Satory, France
关键词
Proton exchange membrane fuel cell; Gas Diffusion Layer; Mechanical properties; Compressive loads; Electrical contact resistances; MEMBRANE FUEL-CELL; DIMENSIONAL CHANGE; STANDARD POROSIMETRY; BIPOLAR PLATE; TRANSPORT; PERFORMANCE; CONDUCTIVITY; PERMEABILITY; PEMFC;
D O I
10.1016/j.ijhydene.2017.03.130
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Recent research has identified the mechanical properties of the fuel cell internal components (in particular, the Gas Diffusion Layers-GDLs) as key-parameters to obtain high final performances of the generator. The mechanical compression modulus of these components, the stability of their mechanical properties with respect to temperature and humidity, and their ability to interact with water have an impact on the electrical contact resistances in the stack and, by consequence, on the overall performance of the electric generator. Reducing the losses by contact resistance is an objective necessary to optimize the fuel cells in operation. The study of GDL electrical behavior under various internal operating conditions provides a suitable database to better understand their effects on the overall stack performance. This paper describes an experimental method for measuring the electrical contact resistance versus the static mechanical pressure applied to the GDLs. A nonlinear behavior of the electrical contact resistance versus the mechanical stress is observed. The PTFE and MPL additions modify the electrical contact resistance. (C) 2017 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:23920 / 23931
页数:12
相关论文
共 37 条
  • [11] Droplet pinning by PEM fuel cell GDL surfaces
    Fishman, J. Zachary
    Leung, Hilary
    Bazylak, A.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (17) : 9144 - 9150
  • [12] Mechanical characterization and analytical modeling of gas diffusion layers under cyclic compression
    Gigos, P. A.
    Faydi, Y.
    Meyer, Y.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2015, 40 (17) : 5958 - 5965
  • [13] Electrical conductivity of PEMFC under loading
    Hamour, M.
    Grandidier, J. C.
    Ouibrahim, A.
    Martemianov, S.
    [J]. JOURNAL OF POWER SOURCES, 2015, 289 : 160 - 167
  • [14] Effects of porosity gradient in gas diffusion layers on performance of proton exchange membrane fuel cells
    Huang, Yu-Xian
    Cheng, Chin-Hsiang
    Wang, Xiao-Dong
    Jang, Jiin-Yuh
    [J]. ENERGY, 2010, 35 (12) : 4786 - 4794
  • [15] A critical review on gas diffusion micro and macroporous layers degradations for improved membrane fuel cell durability
    Lapicque, Francois
    Belhadj, Mariem
    Bonnet, Caroline
    Pauchet, Joel
    Thomas, Yohann
    [J]. JOURNAL OF POWER SOURCES, 2016, 336 : 40 - 53
  • [16] Experimental study of mass transport in PEMFCs: Through plane permeability and molecular diffusivity in GDLs
    Mangal, Prafful
    Pant, Lalit M.
    Carrigy, Nicholas
    Dumontier, Mark
    Zingan, Valentin
    Mitra, Sushanta
    Secanell, Marc
    [J]. ELECTROCHIMICA ACTA, 2015, 167 : 160 - 171
  • [17] A study of the effect of water management and electrode flooding on the dimensional change of polymer electrolyte fuel cells
    Mason, Thomas J.
    Millichamp, Jason
    Neville, Tobias P.
    Shearing, Paul R.
    Simons, Stefaan
    Brett, Daniel J. L.
    [J]. JOURNAL OF POWER SOURCES, 2013, 242 : 70 - 77
  • [18] A study of the effect of compression on the performance of polymer electrolyte fuel cells using electrochemical impedance spectroscopy and dimensional change analysis
    Mason, Thomas J.
    Millichamp, Jason
    Shearing, Paul R.
    Brett, Daniel J. L.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2013, 38 (18) : 7414 - 7422
  • [19] Mechanisms and effects of mechanical compression and dimensional change in polymer electrolyte fuel cells - A review
    Millichamp, Jason
    Mason, Thomas J.
    Neville, Tobias P.
    Rajalakshmi, Natarajan
    Jervis, Rhodri
    Shearing, Paul R.
    Brett, Daniel J. L.
    [J]. JOURNAL OF POWER SOURCES, 2015, 284 : 305 - 320
  • [20] Montanini R, J POWER SOURCES