Flexible and planar graphene conductive additives for lithium-ion batteries

被引:271
作者
Su, Fang-Yuan [1 ]
You, Conghui [1 ]
He, Yan-Bing [1 ,2 ]
Lv, Wei [1 ]
Cui, Wei [1 ]
Jin, Fengmin [1 ]
Li, Baohua [2 ]
Yang, Quan-Hong [1 ,2 ]
Kang, Feiyu [2 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, Minist Educ, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
[2] Tsinghua Univ, Grad Sch Shenzhen, Adv Mat Inst, Shenzhen 518055, Peoples R China
基金
中国国家自然科学基金;
关键词
CARBON-BLACK DISTRIBUTION; ELECTROCHEMICAL PROPERTIES; LIFEPO4; CATHODE; COATED LIFEPO4; LI STORAGE; COMPOSITE; PERFORMANCE; ELECTRODES; NANOSHEETS; NANOTUBES;
D O I
10.1039/c0jm01633k
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Graphene is introduced into a lithium-ion battery (LIB) as a type of novel but powerful planar conductive additive and the flexible graphene-based conducting network is characterized by a novel "plane-to-point" conducting mode with exceptional electron transport properties and unique geometrical nature (a soft and ultrathin planar structure). With a much lower fraction of graphene additives than those of commercial carbon based additives, the graphene-introduced LiFePO(4) cathode shows better charge/discharge performance than commercial cases. Graphene also shows a better performance compared to carbon nanotubes, another type of novel conductive additive with similar fractions. These results present us an indication that graphene will possibly find early application as a flexible and planar conductive additive in high performance LIBs, as our further efforts have shown that a graphene-introduced battery is of better performance as compared to real commercial batteries with conventional additives.
引用
收藏
页码:9644 / 9650
页数:7
相关论文
共 37 条
[1]  
Ball P, 2006, NAT MATER, V5, P434, DOI 10.1038/nmat1660
[2]   Synthesis and electrochemical analysis of vapor-deposited carbon-coated LiFePO4 [J].
Belharouak, I ;
Johnson, C ;
Amine, K .
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (10) :983-988
[3]   Reducing carbon in LiFePO4/C composite electrodes to maximize specific energy, volumetric energy, and tap density [J].
Chen, ZH ;
Dahn, JR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2002, 149 (09) :A1184-A1189
[4]   Influence of carbon sources on electrochemical performances of LiFePO4/C composites [J].
Chen, Zhao-Yong ;
Zhu, Hua-Li ;
Ji, Shan ;
Fakir, Rushanah ;
Linkov, Vladimir .
SOLID STATE IONICS, 2008, 179 (27-32) :1810-1815
[5]   Li-ion batteries from LiFePO4 cathode and anatase/graphene composite anode for stationary energy storage [J].
Choi, Daiwon ;
Wang, Donghai ;
Viswanathan, Vish V. ;
Bae, In-Tae ;
Wang, Wei ;
Nie, Zimin ;
Zhang, Ji-Guang ;
Graff, Gordon L. ;
Liu, Jun ;
Yang, Zhenguo ;
Duong, Tien .
ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (03) :378-381
[6]   The role of carbon black distribution in cathodes for Li ion batteries [J].
Dominko, R ;
Gaberscek, M ;
Drofenik, J ;
Bele, M ;
Pejovnik, S ;
Jamnik, J .
JOURNAL OF POWER SOURCES, 2003, 119 :770-773
[7]   Influence of carbon black distribution on performance of oxide cathodes for Li ion batteries [J].
Dominko, R ;
Gaberscek, M ;
Drofenik, J ;
Bele, M ;
Jamnik, J .
ELECTROCHIMICA ACTA, 2003, 48 (24) :3709-3716
[8]   Diffusion impedance and equivalent circuit of a multilayer film [J].
Freger, V .
ELECTROCHEMISTRY COMMUNICATIONS, 2005, 7 (09) :957-961
[9]   GEOMETRICAL PERCOLATION-THRESHOLD OF OVERLAPPING ELLIPSOIDS [J].
GARBOCZI, EJ ;
SNYDER, KA ;
DOUGLAS, JF ;
THORPE, MF .
PHYSICAL REVIEW E, 1995, 52 (01) :819-828
[10]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191