The Evolution of Decarboxylative Allylation: Overcoming pKa Limitations

被引：28
作者：
Tunge, Jon A. [1 ]
机构：
[1] Univ Kansas, Dept Chem, 1567 Irving Hill Rd, Lawrence, KS 66045 USA
来源：
ISRAEL JOURNAL OF CHEMISTRY | 2020年 / 60卷 / 3-4期
基金：
美国国家科学基金会;
关键词：
decarboxylative; allylation; palladium; photoredox; BOND-DISSOCIATION ENERGIES; C-H BONDS; EQUILIBRIUM ACIDITIES; ALLYLIC ALKYLATION; CARBON ACIDS; ESTERS; GENERATION; KETONES;
D O I：
10.1002/ijch.201900177
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Since early focus on development of the allylation of non-stabilized enolates, decarboxylative allylation has undergone tremendous evolution. This account describes the progression of decarboxylative allylation within the Tunge group with a focus on efforts to identify and overcome pK(a) requirements that initially limited the carboxylates that would undergo decarboxylative allylation.
引用
收藏
页码：351 / 359
页数：9
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