Organo-silica hybrid functional nanomaterials: how do organic bridging groups and silsesquioxane moieties work hand-in-hand?

被引：81

作者：

Hu, Li-Chih ^{[1
]}

Shea, Kenneth J. ^{[1
]}

机构：

[1] Univ Calif Irvine, Dept Chem, Irvine, CA 92697 USA

来源：

CHEMICAL SOCIETY REVIEWS | 2011年 / 40卷 / 02期

关键词：

SOL-GEL SYNTHESIS; INORGANIC MATERIALS; POLYSILSESQUIOXANE NANOPARTICLES; SELF-ORGANIZATION; OXIDE; XEROGELS; POLYMER; UNIFORM; STATE;

D O I：

10.1039/c0cs00219d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Bridged polysilsesquioxanes (BPS) are a class of versatile functional hybrid materials with tunable chemical, physical and mechanical properties. This tutorial review describes recent advances of these functional hybrid nanomaterials. The review includes control of factors affecting nanometre scale morphology, the preparation of spherical hybrid nanoparticles, along with applications in fields including energy, optics and electronics. Special emphasis will be made regarding the synergy between the organic component of the hybrid material and the polysilsesquioxane moieties.

引用

页码：688 / 695

页数：8

共 38 条

[1]

Brinker C.J., 1990, SOL GEL SCI PHYS CHE, P108

[2] PREPARATION OF NANO-SIZED CHROMIUM CLUSTERS AND INTIMATE MIXTURES OF CHROMIUM CDS PHASES IN A POROUS HYBRID XEROGEL BY AN INTERNAL DOPING METHOD [J].