Synthesis and Photophysical Properties of a Novel Hyperbranched Fluorescence Polymer

被引：0
|
作者：
Lue, Xinming [1 ]
Qian, Ying [1 ]
机构：
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 31卷 / 01期
关键词：
hyperbranched fluorecence polymer; Wittig reaction; fluorecence property; fluorecence lifetime; solvatochromic effect; thermal stability; electrochemical property; TRI-BRANCHED COPOLYMERS; CONJUGATED POLYMERS; TRIPHENYLAMINE; UNITS;
D O I：
暂无
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel hyperbranched fluorecence polymer (HPTPA-OXD) containing triphenyamine and 1,3,4-oxadiazole was synthesized by the Wittig reaction. The structure of the polymer was characterized by IR, H-1 NMR and GPC (gel permeation chromatography). The photophysical properties including UV-vis spectra, fluorescence spectra, and fluorescence lifetime were investigated. The maximum emission wavelengths were 473, 497, 507, 522 and 547 nm in toluene, CHCl3, THF, CH2Cl2 and DMF respectively, and the fluorecence lifetime were 1.24, 1.39 and 1.14 ns in THF, CH2Cl2 and DMF respectively. The electrochemical properties was explored by cyclic voltammetry, the HOMO and LUMO energy level of the hyperbranched fluorecence polymer HPTPA-OXD was -4.91 and -2.44 eV, respectively. The polymer HPTPA-OXD showed decomposition temperature 440 degrees C and exhibited good thermal stabilities.
引用
收藏
页码：82 / 86
页数：5
相关论文
共 28 条
  • [1] Array-Based Sensing of Normal, Cancerous, and Metastatic Cells Using Conjugated Fluorescent Polymers
    Bajaj, Avinash
    Miranda, Oscar R.
    Phillips, Ronnie
    Kim, Ik-Bum
    Jerry, D. Joseph
    Bunz, Uwe H. F.
    Rotello, Vincent M.
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2010, 132 (03) : 1018 - 1022
  • [2] Fluorescent conjugated polymers that incorporate substituted 2,1,3-benzooxadiazole and 2,1,3-benzothiadiazole units
    Bouffard, Jean
    Swager, Timothy M.
    [J]. MACROMOLECULES, 2008, 41 (15) : 5559 - 5562
  • [3] Hyperbranched Copolymer Containing Triphenylamine and Divinyl Bipyridyl Units for Fluorescent Chemosensors
    Feng, Jichang
    Li, Yang
    Yang, Mujie
    [J]. JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2009, 47 (01) : 222 - 230
  • [4] FUNCTIONAL POLYMERS AND DENDRIMERS - REACTIVITY, MOLECULAR ARCHITECTURE, AND INTERFACIAL ENERGY
    FRECHET, JMJ
    [J]. SCIENCE, 1994, 263 (5154) : 1710 - 1715
  • [5] Multiple Logic Fluorescent Thermometer System Based on N-Isopropylmethacrylamide Copolymer Bearing Dicyanomethylene-4H-pyran Moiety
    Guo, Zhiqian
    Zhu, Weihong
    Xiong, Yuyan
    Tian, He
    [J]. MACROMOLECULES, 2009, 42 (05) : 1448 - 1453
  • [6] Synthesis of 9-Substituted Fluorene Copolymers via Chemical and Electrochemical Polymer Reaction and Their Optoelectronic Properties
    Hayashi, Shotaro
    Inagi, Shinsulke
    Fuchigami, Toshio
    [J]. MACROMOLECULES, 2009, 42 (11) : 3755 - 3760
  • [7] Hua J. L., 2004, POLYMER, V45, P7143
  • [8] Hwang SH, 2006, DALTON T, P3518, DOI 10.1039/b603691k
  • [9] KAMINORZ Y, 2000, SYNTHETIC MET, V113, P111
  • [10] HYPERBRANCHED POLYPHENYLENES
    KIM, YH
    WEBSTER, OW
    [J]. MACROMOLECULES, 1992, 25 (21) : 5561 - 5572
123