Construction of PANI/Sb2S3 p-n Junction Photoanode for Enhancing Photoelectrochemical Water Oxidation

被引：9
作者：
Liang, Yanqing [1 ]
Wang, Jun [1 ]
Liu, Fangyang [1 ]
Jia, Ming [1 ]
Jiang, Liangxing [1 ]
机构：
[1] Cent South Univ, Sch Met & Environm, Changsha 410083, Hunan, Peoples R China
来源：
JOURNAL OF THE ELECTROCHEMICAL SOCIETY | 2021年 / 168卷 / 06期
关键词：
THIN-FILM; HYDROTHERMAL SYNTHESIS; DEPOSITION; RANGE; TIO2;
D O I：
10.1149/1945-7111/ac064a
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
Antimony sulfide (Sb2S3) is an emerging photovoltaic material that comprises earth-abundant, non-toxic constituents and has a high absorption coefficient (>10(4) cm(-1)). Nevertheless, the serious bulk recombination phenomenon and the slow electrochemical reaction kinetics on the surface of Sb2S3 electrode restrict its application in the photoelectrochemical (PEC) water splitting. Herein, we have designed a polyaniline (PANI)/Sb2S3 p-n junction photoanode successfully to address these issues. With the modification of in-situ anchored PANI, the composite electrode exhibits enhanced light-absorption and accelerated charge transfer efficiency. As a result, the photocurrent density of optimized PANI/Sb2S3 photoanode is about twice of pristine Sb2S3, being a promising material for PEC water splitting.
引用
收藏
页数：6
相关论文
共 50 条
  • [21] Microstructure control of absorber Sb2S3 and p-type semiconductor CuSCN for semiconductor-sensitized solar cells (TiO2/Sb2S3/CuSCN)
    Zhang, Xi
    Yoshioka, Shohei
    Loew, Noya
    Ihara, Manabu
    PHOTOVOLTAICS FOR THE 21ST CENTURY 10, 2014, 64 (15): : 1 - 13
  • [22] Hierarchical TiO2/Fe2O3 heterojunction photoanode for improved photoelectrochemical water oxidation
    Deng, Jiujun
    Zhuo, Qiqi
    Lv, Xiaoxin
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2019, 835 : 287 - 292
  • [23] Cobalt(II)-Imidazoles Passivated α-Fe2O3 Photoanode for Enhanced Photoelectrochemical Water Oxidation
    Han, Hongli
    Chen, Jinxin
    Wen, Liping
    Liu, Jikai
    CATALYSIS LETTERS, 2022, 152 (11) : 3294 - 3303
  • [24] A New Si/TiO2/Pt p-n Junction Semiconductor to Demonstrate Photoelectrochemical CO2 Conversion
    Guaraldo, Thais Tasso
    de Brito, Juliana Ferreira
    Wood, David
    Boldrin Zanoni, Maria Valnice
    ELECTROCHIMICA ACTA, 2015, 185 : 117 - 124
  • [25] One-pot synthesis of TiO2/Sb2S3/RGO complex multicomponent heterostructures for highly enhanced photoelectrochemical water splitting
    Elbakkay, Mohamed H.
    El Rouby, Waleed M. A.
    Marino-Lopez, Andrea
    Sousa-Castillo, Ana
    Salgueirino, Veronica
    El-Dek, S. I.
    Farghali, Ahmed A.
    Correa-Duarte, Miguel A.
    Millet, Pierre
    INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2021, 46 (61) : 31216 - 31227
  • [26] Homogeneous Cu2O p-n junction photocathodes for solar water splitting
    Wang, Tuo
    Wei, Yijia
    Chang, Xiaoxia
    Li, Chengcheng
    Li, Ang
    Liu, Shanshan
    Zhang, Jijie
    Gong, Jinlong
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2018, 226 : 31 - 37
  • [27] Atomic-level thick TiO2-CoTiO3 multilayer p-n junction with extended built-in electric field as efficient photoanode
    Luo, Xuan
    Yang, Fan
    Yan, Lin
    Yang, RuiZhuang
    Zhang, Lin
    CERAMICS INTERNATIONAL, 2022, 48 (01) : 656 - 664
  • [28] Ni(OH)2 functionalized Zr doped α-Fe2O3 photoanode for enhanced photoelectrochemical water oxidation
    Ramachandran, Krishnan
    Pudukudy, Manoj
    Murugan, Angamuthu
    Fu, Yen-Pei
    Ramesh, Rajendran
    INORGANIC CHEMISTRY COMMUNICATIONS, 2022, 146
  • [29] Enhancing the efficiency of Sb2S3 solar cells using dual-functional potassium doping
    Ning, Huan
    Guo, Huafei
    Zhang, Jiayi
    Wang, Xin
    Jia, Xuguang
    Qiu, Jianhua
    Yuan, Ningyi
    Ding, Jianning
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2021, 221
  • [30] Modulation of Energy Band Positions in Sb2S3 Thin Films for Enhanced Photovoltaic Performance of FTO/TiO2/Sb2S3/P3HT/Au Solar Cell
    Gunasekaran, Nithyapremini
    Nagarajan, Deepan Chakravarthi
    Nataraj, Devaraj
    Prabakar, Kandasamy
    ENERGY TECHNOLOGY, 2024,
12345