Two 2D Metal-organic Networks Based on a Rigid Imidazolate/Sulfonate Functionalized Ligand - Effect of the Coordination Modes of the Ligand on Crystal Structures

被引：1

作者：

Wang, Xiu-Ying ^{[1
]}

Xu, Long ^{[1
]}

Liu, Rui-Bin ^{[1
]}

Liu, Shu-Qin ^{[1
]}

Yang, Wen-Bo ^{[1
]}

Zhang, Jian-Jun ^{[1
]}

机构：

[1] Dalian Univ Technol, Chem Coll, Dalian 116024, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2012年 / 638卷 / 06期

基金：

中国国家自然科学基金;

关键词：

Supramolecular chemistry; Coordination polymers; Self-assembly; Sulfonate; Coordination modes; GAS-SORPTION; FRAMEWORKS; COMPLEXES; TRANSITION; BEHAVIOR; STORAGE; CHAIN; ACID;

D O I：

10.1002/zaac.201100528

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A rigid imidazolate/sulfonate functionalized ligand, 6-(4-sulfonatopheny)imidazo[4, 5-f]isoindole-5, 7-dione (SPID) was designed and used for assembling reactions with Mn2+ and Cu2+ ions. Two 2D frameworks compounds, [Mn(H-1SPID)2(DMAC)2] (1) and [Cu(H-2SPID)(H2O)2]center dot 0.7DMAC center dot 0.3H2O (2) (DMAC = N,N-dimethylacetamide) were obtained. Single crystal X-ray analyses show that 1 has a 2D (4, 4)-net based on 4-connected Mn2+ nodes and mu 2-coordinated H-1SPID spacers, whereas compound 2 has a 2D (6, 3)-net built of 3-connected Cu2+ nodes and mu 3-coordinated H-2SPID spacers. Additionally, the thermal behavior of 1 and 2 is presented.

引用

页码：1006 / 1011

页数：6

共 59 条

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