High-performance ZrO2-coated LiNiO2 cathode material

被引：117
作者：
Cho, J [1 ]
Kim, TJ
Kim, YJ
Park, B
机构：
[1] Samsung SDI Co Ltd, Energy Lab, Cheonan, Chungchongnam D, South Korea
[2] Seoul Natl Univ, Sch Mat Sci & Engn, Seoul, South Korea
来源：
ELECTROCHEMICAL AND SOLID STATE LETTERS | 2001年 / 4卷 / 10期
关键词：
D O I：
10.1149/1.1398556
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
LiNiO2 with excellent structural stability and electrochemical reversibility is obtained by sol-gel coating of ZrO2. Significantly reduced lattice distortion is found in ZrO2-coated LiNiO2, showing several-times-lower changes in the lattice constants during charging, compared to that of bare sample. The thin-film encapsulation by ZrO2, with higher Zr concentration at the particle surface within similar to1 mum, can effectively suppress the lattice distortion and thereby phase transitions. The improved electrochemical reversibility is well demonstrated by the cycle-life performance in the coin-type half-cells (Li/coated-LiNiO2 and Li/bare-LiNiO2) between 4.3 and 2.75 V, showing only 2% capacity loss in the ZrO2-coated sample after 70 cycles. (C) 2001 The Electrochemical Society.
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页码：A159 / A161
页数：3
相关论文
共 18 条
[1]  
CALLISTER WD, 1997, MAT SCI ENG INTRO, P787
[2]   LiNi0.74Co0.26-xMgxO2 cathode material for a Li-ion cell [J].
Cho, J .
CHEMISTRY OF MATERIALS, 2000, 12 (10) :3089-3094
[3]   Effect of preparation methods of LiNi1-xCoxO2 cathode materials on their chemical structure and electrode performance [J].
Cho, J ;
Kim, G ;
Lim, HS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1999, 146 (10) :3571-3576
[4]   Enhanced structural stability of o-LiMnO2 by sol-gel coating of Al2O3 [J].
Cho, J ;
Kim, YJ ;
Kim, TJ ;
Park, B .
CHEMISTRY OF MATERIALS, 2001, 13 (01) :18-+
[5]   Novel LiCoO2 cathode material with Al2O3 coating for a Li ion cell [J].
Cho, J ;
Kim, YJ ;
Park, B .
CHEMISTRY OF MATERIALS, 2000, 12 (12) :3788-3791
[6]   Electrochemical properties and thermal stability of LiaNi1-xCoxO2 cathode materials [J].
Cho, JP ;
Jung, HS ;
Park, YC ;
Kim, GB ;
Lim, HS .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (01) :15-20
[7]   THE CYCLING PROPERTIES OF THE LIXNI1-YCOYO2 ELECTRODE [J].
DELMAS, C ;
SAADOUNE, I ;
ROUGIER, A .
JOURNAL OF POWER SOURCES, 1993, 44 (1-3) :595-602
[8]  
Dokko K, 2000, ELECTROCHEM SOLID ST, V3, P125
[9]  
Gao YA, 1998, ELECTROCHEM SOLID ST, V1, P117, DOI 10.1149/1.1390656
[10]   Effects of sintering temperature on the structure of the layered phase Lix(Ni0.8Co0.2)O2 [J].
Gover, RKB ;
Kanno, R ;
Mitchell, BJ ;
Yonemura, M ;
Kawamoto, Y .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (11) :4045-4051
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