Bronsted Acidic Ionic Liquids Mediated Metallic Salts Catalytic System for the Chemical Fixation of Carbon Dioxide to Form Cyclic Carbonates

被引：37
|
作者：
Xiao, Linfei [1 ,2 ]
Lv, Dongwei [1 ,2 ]
Wu, Wei [1 ,2 ]
机构：
[1] Heilongjiang Univ, Key Lab Funct Inorgan Mat Chem, Minist Educ, Coll Heilongjiang Prov,Sch Chem & Mat Sci, Harbin 150080, Peoples R China
[2] Heilongjiang Univ, Key Lab Chem Engn Proc & Technol High Efficiency, Coll Heilongjiang Prov, Sch Chem & Mat Sci, Harbin 150080, Peoples R China
来源：
CATALYSIS LETTERS | 2011年 / 141卷 / 12期
基金：
黑龙江省自然科学基金;
关键词：
Bronsted acidic ionic liquids; Carbon dioxide; Epoxide; Cyclic carbonate; HIGHLY EFFICIENT; COUPLING REACTIONS; HETEROGENEOUS CATALYST; PROPYLENE CARBONATE; EPOXIDES; CO2; OXIDE; TRANSFORMATION; ACTIVATION; OXIDATION;
D O I：
10.1007/s10562-011-0682-3
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The catalysts of COOH- and SO3H-functionalized ionic liquids mediated metallic salts had been developed for the coupling of carbon dioxide and epoxides to form cyclic carbonates under mild reaction conditions without using additional organic solvents. The effects of different ionic liquids, metallic salts, varying the molar ratio of ionic liquid to metallic salt and reaction conditions were examined. The excellent yield of cyclic carbonates and the high turnover frequencies (TOF) were obtained at the optimum reaction conditions. In addition, the catalytic system offered high stability and reusability.
引用
收藏
页码：1838 / 1844
页数：7
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