Preparation of Expandable Graphite and Its Flame Retardant Properties in HDPE Composites

被引:12
作者
Shen, Ming-Yuan [1 ]
Chen, Wei-Jen [1 ]
Tsai, Kuang-Chung [2 ]
Kuan, Chen-Feng [3 ]
Kuan, Hsu-Chiang [3 ]
Chou, Huang-Wen [4 ]
Chiang, Chin-Lung [4 ]
机构
[1] China Univ Sci & Technol, Dept Aviat Mech Engn, Hukou Township 303, Hsinchu County, Taiwan
[2] Natl Kaohsiung First Univ Sci & Technol, Dept Safety Hlth & Environm Engn, Kaohsiung 811, Taiwan
[3] Far East Univ, Dept Comp Applicat Engn, Tainan 744, Taiwan
[4] Hung Kuang Univ, Green Flame Retardant Mat Res Lab, Dept Safety Hlth & Environm Engn, Taichung 433, Taiwan
关键词
DENSITY POLYETHYLENE; ACTIVATED CARBON; INTUMESCENT; HYDROXIDE; MECHANISM; HAZARD; OZONE; AGENT;
D O I
10.1002/pc.23820
中图分类号
TB33 [复合材料];
学科分类号
摘要
This study showed an efficient and novel way to prepare expandable graphite (EG) which is one kind of halogen-free flame retardant using the O-3-hydrothermal process. The results showed the expanded volume of EG using the O-3-hydrothermal process was higher than those compared to convectional liquid phase synthesis, ultrasound irradiation and hydrothermal method. X-ray diffraction pattern, Fourier transform infrared spectroscopy, and X-ray photoelectron spectroscopy were used to analyze the structure and confirm that EG had been prepared. Scanning electron microscope was utilized to observe the morphology of EG and char from HDPE/O-3-HEG composites. Cone calorimeter, limiting oxygen index, and UL-94 were used to investigate the flame retardant property of the HDPE/O-3-HEG composites and showed the HDPE/O-3-HEG composite possesses excellent flame retardant property. (C) 2015 Society of Plastics Engineers
引用
收藏
页码:2378 / 2386
页数:9
相关论文
共 27 条
  • [1] HEAT RELEASE RATE - THE SINGLE MOST IMPORTANT VARIABLE IN FIRE HAZARD
    BABRAUSKAS, V
    PEACOCK, RD
    [J]. FIRE SAFETY JOURNAL, 1992, 18 (03) : 255 - 272
  • [2] Babrauskas V., 1995, Fire Mater, V19, P243, DOI [10.1002/fam.810190602, DOI 10.1002/FAM.810190602]
  • [3] Camino G., 2001, MAT SOLUTIONS HAZARD, P90
  • [4] The surface characteristics of activated carbon as affected by ozone and alkaline treatment
    Chiang, HL
    Huang, CP
    Chiang, PC
    [J]. CHEMOSPHERE, 2002, 47 (03) : 257 - 265
  • [5] Chuang T.H., 1999, P 3 BEIJ INT S FLAM, P239
  • [6] Spent refinery catalyst as a synergistic agent in intumescent formulations: influence of the catalyst's particle size and constituents
    Estevao, LRM
    Le Bras, M
    Delobel, R
    Nascimento, RSV
    [J]. POLYMER DEGRADATION AND STABILITY, 2005, 88 (03) : 444 - 455
  • [7] An Antidripping Flame Retardant Finishing for Polyethylene Terephthalate Fabric
    Feng, Qingli
    Gu, Xiaoyu
    Zhang, Sheng
    Zhao, Bin
    Sun, Jun
    Li, Xueyan
    Dong, Mingzhe
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2012, 51 (45) : 14708 - 14713
  • [8] Synergistic flame retardant mechanism of fumed silica in ethylene-vinyl acetate/magnesium hydroxide blends
    Fu, MZ
    Qu, BJ
    [J]. POLYMER DEGRADATION AND STABILITY, 2004, 85 (01) : 633 - 639
  • [9] A flame-retardant epoxy resin based on a reactive phosphorus-containing monomer of DODPP and its thermal and flame-retardant properties
    Gao, Li-Ping
    Wang, De-Yi
    Wang, Yu-Zhong
    Wang, Jun-Sheng
    Yang, Bing
    [J]. POLYMER DEGRADATION AND STABILITY, 2008, 93 (07) : 1308 - 1315
  • [10] Synthetic hydromagnesite as flame retardant.: Evaluation of the flame behaviour in a polyethylene matrix
    Haurie, L
    Fernández, AI
    Velasco, JI
    Chimenos, JM
    Cuesta, JML
    Espiell, F
    [J]. POLYMER DEGRADATION AND STABILITY, 2006, 91 (05) : 989 - 994