A chiral metal-organic framework for sequential asymmetric catalysis

被引：175

作者：

Song, Feijie ^{[1
]}

Wang, Cheng ^{[1
]}

Lin, Wenbin ^{[1
]}

机构：

[1] Univ N Carolina, Dept Chem, Chapel Hill, NC 27599 USA

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 29期

基金：

美国国家科学基金会;

关键词：

NANOSCALE COORDINATION POLYMERS; HYDROGEN STORAGE; DRUG-DELIVERY; HYBRID SOLIDS; EPOXIDATION; SITES; CATENATION; COMPLEXES; NETWORKS; PLATFORM;

D O I：

10.1039/c1cc12701b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral metal-organic framework (MOF) of the lcy topology was constructed from the Mn-Salen derived dicarboxylic acid and the [Zn(4)(mu(4)-O)(O(2)CR)(6)] secondary building unit, and used in highly regio- and stereo-selective sequential alkene epoxidation/epoxide ring-opening reactions.

引用

页码：8256 / 8258

页数：3

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