IR spectroscopic study of chemical transformations upon irradiation of the poly(vinyl chloride) - Triallyl cyanurate system

被引：1

作者：

Shmakova, NA

Feldman, VI

Sukhov, FF

机构：

[1] Russian Acad Sci, Inst Synthet Polymer Mat, Moscow 117393, Russia

[2] Russian Fed Res Ctr, Karpov Inst Phys Chem, Moscow 103064, Russia

来源：

HIGH ENERGY CHEMISTRY | 2001年 / 35卷 / 04期

关键词：

Spectroscopy; Irradiation Dose; Vinyl; Network Structure; Scission;

D O I：

10.1023/A:1017628410368

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Chemical transformations resulting from irradiation of the poly(vinyl chloride) (PVC)-triallyl cyanurate (TAC) system were studied by IR spectroscopy. It was shown that crosslinking was accompanied by scission of the network structure formed in the initial dose range, and the scission process occurred even at small irradiation doses. The scission is assumed to be localized at the interface boundary between PVC and poly(iso-TAC) or poly(TAC).

引用

页码：224 / 228

页数：5

共 9 条

[1]

Bellamy LJNY., 2013, INFRA RED SPECTRA CO

[2]

BORT DN, 1965, DOKL AKAD NAUK SSSR+, V160, P413

[3] POLYMERIZATION OF TRIALLYL CYANURATE [J].

CLAMPITT, BH ;

GERMAN, DE ;

GALLI, JR .

JOURNAL OF POLYMER SCIENCE, 1958, 27 (115) :515-522

[4] Radiation-induced network formation in polyvinyl chloride polyfunctional monomer systems [J].

Dakin, VI .

RADIATION PHYSICS AND CHEMISTRY, 1996, 48 (03) :343-348

[5]

DAKIN VI, 1977, KHIM VYS ENERG, V11, P379

[6]

DAKIN VI, 1984, VYSOKOMOL SOEDIN A, V24, P2211

[7] ENHANCEMENT OF RADIATION-INDUCED CROSS-LINKING OF POLYVINYL CHLORIDE [J].

PINNER, SH .

NATURE, 1959, 183 (4668) :1108-1109

[8]

SUKHOV FF, 1973, J POLYM SCI POL SYM, P147

[9]

TEPLOV BF, 1971, VYSOKOMOL SOEDIN A, V13, P2422

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