Dipole moment and spontaneous polarization of ferroelectric nanoparticles in a nonpolar fluid suspension

被引:61
作者
Basun, S. A. [1 ,2 ]
Cook, G. [1 ,3 ]
Reshetnyak, V. Yu. [4 ]
Glushchenko, A. V. [5 ]
Evans, D. R. [1 ]
机构
[1] USAF, Res Lab, Mat & Mfg Directorate, Wright Patterson AFB, OH 45433 USA
[2] Universal Technol Corp, Dayton, OH 45432 USA
[3] Azimuth Corp, Dayton, OH 45432 USA
[4] Natl Taras Shevchenko Univ Kyiv, UA-01601 Kiev, Ukraine
[5] Univ Colorado, Colorado Springs, CO 80918 USA
关键词
PHASE-TRANSITION; BARIUM-TITANATE; SURFACE; FILMS; LIGHT; SIZE;
D O I
10.1103/PhysRevB.84.024105
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Stressed ferroelectric nanoparticles, less than 10 nm in diameter, are investigated in a nonpolar fluid. Measuring ferroelectric properties of the smallest achieved BaTiO3 ferroelectric nanoparticles allows for the determination of dipole moment and spontaneous polarization as a function of size and concentration; the results are significantly greater than in bulk BaTiO3. This is achieved by using a direct measurement of the displacement current density and either integrating over half a period or fitting the experimental results using the derivative of the Langevin function.
引用
收藏
页数:8
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