Volume of electrostriction of the solvate-separated ions of lithium perchlorate and contact ion pair of the transition state in sulfenyl insertion

被引：9

作者：

Kiselev, Vladimir D. ^{[1
]}

机构：

[1] Kazan VI Lenin State Univ, AM Butlerov Chem Inst, Kazan 420008, Russia

来源：

MENDELEEV COMMUNICATIONS | 2008年 / 18卷 / 01期

基金：

俄罗斯基础研究基金会;

关键词：

D O I：

10.1016/j.mencom.2008.01.022

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The volumes of electrostriction of the ions of lithium perchlorate are in a linear relation with the solvent electrostriction parameter partial derivative(1/epsilon)/partial derivative p but the volume changes of ion pair transition state of electrophilic addition of aryl sulfenyl chloride to styrene andcyclohexene have the slope about 20 times less.

引用

页码：59 / 61

页数：3

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