Hydration of α-pinene over molybdophosphoric acid immobilized in hydrophobically modified PVA membranes

被引:39
作者
Castanheiro, JE [1 ]
Fonseca, IM [1 ]
Ramos, AM [1 ]
Oliveira, R [1 ]
Vital, J [1 ]
机构
[1] Univ Nova Lisboa, REQUIMTE, Fac Ciencias & Tecnol, CQFB, P-2829516 Caparica, Portugal
关键词
polymeric catalytic membranes; poly(vinyl alcohol); acetylation; heteropolyacids; molybdophosphoric acid; USY; alpha-pinene hydration;
D O I
10.1016/j.cattod.2005.03.077
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A polyvinylalcohol/molybdophosphoric acid (PVA/HPMo) membrane crosslinked with succinic acid was modified by treatment with acetic anhydride in order to improve its hydrophobic properties, and was used as catalyst in the hydration reaction of alpha-pinene. The increase of membrane hydrophobicity with acetylation is documented not only by the water droplet contact angle but also by the sorption coefficients of alpha-pinene and water. The introduction of acetyl groups improves the membrane transport properties, as reflected by pinene diffusivity calculated from permeation data. A kinetic-diffusion model was developed assuming that the reaction product a-terpineol affects the transport of water and a-pinene across the acetylated PVA membranes. When membrane acetylation increases, the model predicted kinetic constants for hydration and isomerization reactions decrease, although the initial water diffusivity increases. These results suggest that the increase of catalytic activity may be due to an improvement of water transport across the membrane. (c) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:296 / 304
页数:9
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