Zn-doped TiO2 nanoparticles with high photocatalytic activity synthesized by hydrogen-oxygen diffusion flame

被引：202

作者：

Zhao, Yin ^{[1
,2
]}

Li, Chunzhong ^{[1
]}

Liu, Xiuhong ^{[1
]}

Go, Feng ^{[1
]}

Du, H. L. ^{[3
]}

Shi, Liyi ^{[2
]}

机构：

[1] E China Univ Sci & Technol, Key Lab Ultrafine Mat, Minist Educ, Sch Mat Sci & Engn, Shanghai 200237, Peoples R China

[2] Shanghai Univ, Res Ctr Nanosci & Nanotechnol, Shanghai 200436, Peoples R China

[3] Northumbria Univ, Adv Mat Res Inst, Newcastle Upon Tyne NE1 8ST, Tyne & Wear, England

来源：

APPLIED CATALYSIS B-ENVIRONMENTAL | 2008年 / 79卷 / 03期

关键词：

titanium dioxide; photocatalytic; nanoparticles; zinc oxide; dopant; gas flame combustion; surface oxygen vacancies;

D O I：

10.1016/j.apcatb.2007.09.044

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Zn-doped TiO2 nanoparticles with high photocatalytic activity were synthesized by the hydrogen-oxygen diffusion flame method and the photocatalytic degradation mechanism of rhodamine B dye under visible light irradiation were elaborated. The Zn dopants presented in the form of small ZnO nuclei dispersing randomly on the surface of anatase TiO2 nanoparticles. It is found that the photosensitized degradation activity can be enhanced by doping an appropriate amount of Zn. The improved activity by Zn doping can be attributed to the appropriate energetic position between ZnO and the excited state of dye, which enhanced the electron injection into the conduction band of TiO2 by capturing electron, subsequently promoted the formation of reactive oxygen species. Hence, the enhanced photodegradation of dyes under visible irradiation can be realized. (C) 2007 Elsevier B.V. All rights reserved.

引用

页码：208 / 215

页数：8

共 32 条

[1] Visible-light photocatalysis in nitrogen-doped titanium oxides [J].