N-heterocyclic carbene palladium(II)-catalyzed Suzuki-Miyaura cross coupling of N-acylsuccinimides by C-N cleavage

被引：16
作者：
Wang, Tao [1 ,2 ]
Guo, Jiarui [1 ,2 ]
Wang, Hengjin [1 ,2 ]
Guo, Han [1 ,2 ]
Jia, Dingli [1 ,2 ]
Zhang, Wen [1 ,2 ]
Liu, Lantao [1 ,2 ]
机构：
[1] Shangqiu Normal Univ, Sch Chem & Chem Engn, Henan Engn Lab Green Synth Pharmaceut, Shangqiu 476000, Henan, Peoples R China
[2] Shangqiu Normal Univ, Sch Chem & Chem Engn, Henan Key Lab Biomol Recognit & Sensing, Shangqiu 476000, Henan, Peoples R China
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2018年 / 877卷
基金：
中国国家自然科学基金;
关键词：
ACYL-TRANSFER REAGENTS; CARBOXYLIC ANHYDRIDES; ORGANOBORON COMPOUNDS; ARYLBORONIC ACIDS; CARBENE-PALLADIUM(II) COMPLEXES; KETONE SYNTHESIS; BOND ACTIVATION; O BONDS; ESTERS; AMIDES;
D O I：
10.1016/j.jorganchem.2018.09.026
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An easily prepared, well-defined N-heterocyclic carbene-palladium(II) complex was found to be an efficient catalyst for the Suzuki-Miyaura cross-coupling of N-acylsuccinimides with arylboronic acids via C-N bond activation. Under the optimal conditions, all reactions proceeded smoothly generating broad array of diaryl ketones in good to high yields (81->99%) within hours. (c) 2018 Elsevier B.V. All rights reserved.
引用
收藏
页码：80 / 84
页数：5
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