Palladium-catalyzed carbonylative synthesis of 3-arylquinolin-2(1H)-ones from benzyl chlorides and o-nitrobenzaldehydes

被引：7
|
作者：
Liu, Jian-Li [1 ]
Hou, Chen-Yang [1 ]
Qi, Xinxin [1 ]
Wu, Xiao-Feng [2 ,3 ]
机构：
[1] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China
[2] Chinese Acad Sci, Dalian Inst Chem Phys, Dalian Natl Lab Clean Energy, Dalian 116023, Liaoning, Peoples R China
[3] Leibniz Inst Katalyse eV, Albert Einstein Str 29a, D-18059 Rostock, Germany
来源：
MOLECULAR CATALYSIS | 2021年 / 514卷
关键词：
Palladium catalyst; Carbonylation; Benzyl chloride; O-nitrobenzaldehyde; Quinolinones; IN-VIVO; GLYCINE SITE; QUINOLINONES; QUINOLIN-2(1H)-ONES; AMINOCARBONYLATION; ANTIBACTERIAL; 2-QUINOLONES; DERIVATIVES; ANTAGONISTS; ANNULATION;
D O I：
10.1016/j.mcat.2021.111842
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
A palladium-catalyzed carbonylative cyclization of benzyl chlorides with o-nitrobenzaldehydes has been developed for the synthesis of 3-arylquinolin-2(1H)-ones. Mo(CO)(6) played a dual role as both a CO surrogate and a reductant in this carbonylative transformation.
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页数：4
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