Emerging strategies in sustainable fine-chemical synthesis: asymmetric catalysis by metal nanoparticles

被引：38

作者：

Barbaro, Pierluigi ^{[1
]}

Dal Santo, Vladimiro ^{[2
]}

Liguori, Francesca ^{[1
]}

机构：

[1] ICCOM CNR, I-50019 Florence, Italy

[2] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 36期

关键词：

ENANTIOSELECTIVE BORANE REDUCTION; ORDERED MESOPOROUS POLYMERS; MODIFIED PLATINUM CATALYSTS; SILICA-SUPPORTED CATALYSTS; PT-ALUMINA CATALYST; PALLADIUM NANOPARTICLES; ETHYL PYRUVATE; SELECTIVE HYDROGENATION; ALPHA-KETOESTERS; OPTICAL-ACTIVITY;

D O I：

10.1039/c002051f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of chiral-and nano-technologies is potentially one of the most promising strategies for "green" catalytic conversions aimed at fine-chemical production. This paper reviews the most representative examples and highlights recent achievements in the field of enantioselective processes catalyzed by metal nanoparticles (MNPs), with a view to the potential of the methodology and future perspectives. Applications are described according to the nanocatalyst type used, either liquid-phase suspensions or solid-supported systems. The focus is on the design of the catalysts, their preparation and characterization, applications in catalysis and mechanistic studies.

引用

页码：8391 / 8402

页数：12

共 144 条

[11] Hydrogenation of arenes over silica-supported catalysts that combine a grafted rhodium complex and palladium nanoparticles:: Evidence for substrate activation on Rhsingle-site-Pdmetal moieties [J].