Emerging strategies in sustainable fine-chemical synthesis: asymmetric catalysis by metal nanoparticles

被引：38

作者：

Barbaro, Pierluigi ^{[1
]}

Dal Santo, Vladimiro ^{[2
]}

Liguori, Francesca ^{[1
]}

机构：

[1] ICCOM CNR, I-50019 Florence, Italy

[2] CNR, Ist Sci & Tecnol Mol, I-20133 Milan, Italy

来源：

DALTON TRANSACTIONS | 2010年 / 39卷 / 36期

关键词：

ENANTIOSELECTIVE BORANE REDUCTION; ORDERED MESOPOROUS POLYMERS; MODIFIED PLATINUM CATALYSTS; SILICA-SUPPORTED CATALYSTS; PT-ALUMINA CATALYST; PALLADIUM NANOPARTICLES; ETHYL PYRUVATE; SELECTIVE HYDROGENATION; ALPHA-KETOESTERS; OPTICAL-ACTIVITY;

D O I：

10.1039/c002051f

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The combination of chiral-and nano-technologies is potentially one of the most promising strategies for "green" catalytic conversions aimed at fine-chemical production. This paper reviews the most representative examples and highlights recent achievements in the field of enantioselective processes catalyzed by metal nanoparticles (MNPs), with a view to the potential of the methodology and future perspectives. Applications are described according to the nanocatalyst type used, either liquid-phase suspensions or solid-supported systems. The focus is on the design of the catalysts, their preparation and characterization, applications in catalysis and mechanistic studies.

引用

收藏

页码：8391 / 8402

页数：12

相关论文

共 144 条

[1] Platinum nanoparticles supported on ionic liquid-modified magnetic nanoparticles: Selective hydrogenation catalysts [J].

Abu-Reziq, Raed ;

Wang, Dashan ;

Post, Michael ;

Alper, Howard .

ADVANCED SYNTHESIS & CATALYSIS, 2007, 349 (13) :2145-2150

[2]

Amabilino D. B., 2009, CHIRALITY NANOSCALE

[3]

[Anonymous], 2007, NANOPARTICLE CATALYS

[4] Nanoparticles as recyclable catalysts: The frontier between homogeneous and heterogeneous catalysis [J].

Astruc, D ;

Lu, F ;

Aranzaes, JR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (48) :7852-7872

[5] Reflections on chiral metal surfaces and their potential for catalysis [J].

Baiker, A .

CATALYSIS TODAY, 2005, 100 (1-2) :159-170

[6] Heterogeneous asymmetric reactions -: Part 40.: New data on repeated use of Pt-alumina catalyst during enantioselective hydrogenation of ethyl pyruvate [J].

Balázsik, K ;

Bartók, M .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 219 (02) :383-389

[7] Methylethers of cinchona alkaloids in Pt-catalyzed hydrogenation of methyl benzoylformate and pyruvaldehyde dimethyl acetal -: Part 2:: Effect of stereochemical factors on the enantioselectivity [J].

Balazsik, Katalin ;

Bucsi, Imre ;

Cserenyi, Szabolcs ;

Szoellosi, Gyoergy ;

Bartok, Mihaly .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 285 (1-2) :84-91

[8] Methylethers of cinchona alkaloids in Pt-catalyzed hydrogenation of ethyl pyruvate and ketopantolactone:: Effect of stereochemical factors on the enantioselectivity [J].

Balazsik, Katalin ;

Bucsi, Imre ;

Cserenyi, Szabolcs ;

Szoellosi, Gyoergy ;

Bartok, Mihaly .

JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2008, 280 (1-2) :87-95

[9]

BARBARO P, 2008, 2 IDECAT C CAT CONC

[10] Benzene hydrogenation by silica-supported catalysts made of palladium nanoparticles and electrostatically immobilized rhodium single sites [J].

Barbaro, Pierluigi ;

Bianchini, Claudio ;

Dal Santo, Vladimiro ;

Meli, Andrea ;

Moneti, Simonetta ;

Pirovano, Claudio ;

Psaro, Rinaldo ;

Sordelli, Laura ;

Vizza, Francesco .

ORGANOMETALLICS, 2008, 27 (12) :2809-2824

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