Super broadband near-infrared luminescence in Ni2+-Er3+ co-doped transparent glass ceramics

被引:9
作者
Zheng, Jian [1 ]
Cheng, Yin [1 ]
Deng, Zhuoer [1 ]
Xiong, Yin [1 ]
机构
[1] Changsha Univ Sci & Technol, Coll Mat Sci & Engn, Changsha 410004, Hunan, Peoples R China
关键词
Ni2+; Er3+; Transparent glass ceramics; Luminescence; ENERGY-TRANSFER; SPECTROSCOPIC PROPERTIES; EMISSION; FLUORESCENCE; NI2+; ION;
D O I
10.1016/j.jnoncrysol.2017.06.039
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Ni2+-Er3+ co-doped glass ceramics containing ZnGa2O4 nanocrystals were fabricated by in situ controlled crystallization method. The adverse energy transfer between Ni2+ and Er3+ could be suppressed in the ZnGa2O4 glass ceramics. And the super-broadband infrared luminescence with full width at half maximum (FWHM) of about 400 nm covering 1.1-1.7 mu m wavelength region was observed in Ni2+-Er3+ co-doped glass ceramics. The two lifetimes of 1NE-GC950 revealed that two luminescence mechanism involved in the luminescence process, Ni2+:T-3(2g) (F-3) -> (3)A(2g) (F-3) and Er3+:I-4(13/2) -> I-4(15/2) respectively. Compared to that in the Ni2+/Er3+ co-doped glass ceramic containing gamma-Ga2O3 and LaF3 nanocrystals, the nanocrystals in the present paper is just only one, ZnGa2O4 nanocrystals, and it could also present super-broadband luminescence.
引用
收藏
页码:446 / 451
页数:6
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