Ultrahigh Energy Density of Polymer Nanocomposites Containing BaTiO3@TiO2 Nanofibers by Atomic-Scale Interface Engineering

被引:527
作者
Zhang, Xin [1 ]
Shen, Yang [1 ]
Zhang, Qinghua [1 ]
Gu, Lin [2 ]
Hu, Yuhan [1 ]
Du, Jiawen [1 ]
Lin, Yuanhua [1 ]
Nan, Ce-Wen [1 ]
机构
[1] Tsinghua Univ, Sch Mat Sci & Engn, State Key Lab New Ceram & Fine Proc, Beijing 100084, Peoples R China
[2] Chinese Acad Sci, Inst Phys, Beijing Natl Lab Condensed Matter Phys, Beijing 100190, Peoples R China
关键词
dielectric; energy density; interfaces; nanocomposites; nanofibers; BREAKDOWN STRENGTH; STORAGE; CAPACITORS; SUPERLATTICES; PERMITTIVITY; POLARIZATION; DIELECTRICS; COMPOSITES; NANOWIRES;
D O I
10.1002/adma.201404101
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Atomic-scale interface engineering in BaTiO3@TO2 nanofibers (TiO2 nanofibers embedded with BaTiO3 nanoparticles) leads to concurrent enhancement of electric displacement and breakdown strength in poly(vinylidene fluoride) (PVDF)-based nanocomposites. An ultrahigh energy density of approximate to 20 J cm-(3) is achieved with only 3 vol% nanofibers, which is by far the highest discharged energy density of PVDF-based nanocomposites.
引用
收藏
页码:819 / 824
页数:6
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