A facile analytical method for reliable selectivity examination in cofactor NADH regeneration

被引：67
作者：
Saba, Tony [1 ]
Burnett, Joseph W. H. [1 ]
Li, Jianwei [1 ]
Kechagiopoulos, Panagiotis N. [1 ]
Wang, Xiaodong [1 ,2 ]
机构：
[1] Univ Aberdeen, Sch Engn, Chem & Mat Engn, Aberdeen AB24 3UE, Scotland
[2] Univ Lancaster, Dept Engn, Lancaster LA1 4YW, England
来源：
CHEMICAL COMMUNICATIONS | 2020年 / 56卷 / 08期
关键词：
ELECTROCHEMICAL REGENERATION; REDUCTION; RHODIUM; COMPLEXES; PRODUCTS; DIOXIDE; LIGHT; DPN+;
D O I：
10.1039/c9cc07805c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
This study demonstrates a novel method to quantify selective (1,4-NADH) and unselective products (1,2- and 1,6-NADH) in NADH regeneration using combined UV-Vis spectroscopy and biological assays. The validity of the proposed method was tested in the Pt/C promoted NAD(+) hydrogenation using hydrogen as reducing agent.
引用
收藏
页码：1231 / 1234
页数：4
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