Lanthanum doped BiFeO3 powders: Syntheses and characterization

被引:62
作者
Gonzalez Garcia, F. [1 ]
Riccardi, C. S. [2 ]
Simoes, A. Z. [1 ]
机构
[1] Univ Fed Itajuba Unifei, BR-35900373 Itabira, MG, Brazil
[2] Univ Estadual Paulista, Inst Quim, Dept Quim Fis, Lab Interdisciplinar Ceram, BR-14800900 Araraquara, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Ferroelectrics; Chemical syntheses; Powder metallurgy; X-ray diffraction; THIN-FILMS; ROOM-TEMPERATURE; FERROELECTRIC POLARIZATION; SILLENITES; FERRITE;
D O I
10.1016/j.jallcom.2010.04.049
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A soft chemistry route was employed to fabricate single-phase lanthanum modified BiFeO3 (BFO) powders. Effects of lanthanum concentration on the phase formation, grain size and morphologies of BFO powders were systematically investigated. X-ray diffraction results indicated that perovskite phase have been synthesized at the temperature of 850 degrees C/2 h while infrared data indicates no traces of carbonate. Raman analysis reveals that lanthanum atom substitutes bismuth into the BFO site. A homogeneous size distribution of BFO powders was evidenced by scanning electron microscopy. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码:25 / 29
页数:5
相关论文
共 24 条
[1]   Effect of La3+ substitution on the structural, electrical and electrochemical properties of strontium ferrite by citrate combustion method [J].
Augustin, CO ;
Selvan, RK ;
Nagaraj, R ;
Berchmans, LJ .
MATERIALS CHEMISTRY AND PHYSICS, 2005, 89 (2-3) :406-411
[2]   Band gap tuning of lead-substituted BaSnO3 for visible light photocatalysis [J].
Borse, Pramod H. ;
Joshi, Upendra A. ;
Ji, Sang Min ;
Jang, Jum Suk ;
Lee, Jae Sung ;
Jeong, Euh Duck ;
Kim, Hyun Gyu .
APPLIED PHYSICS LETTERS, 2007, 90 (03)
[3]   Study of structural evolution and photoluminescent properties at room temperature of Ca(Zr, Ti)O3 powders [J].
Cavalcante, L. S. ;
Simoes, A. Z. ;
Espinosa, J. W. M. ;
Santos, L. P. S. ;
Longo, E. ;
Varela, J. A. ;
Pizani, P. S. .
JOURNAL OF ALLOYS AND COMPOUNDS, 2008, 464 (1-2) :340-346
[4]   Structure, ferroelectric properties, and magnetic properties of the La-doped bismuth ferrite [J].
Cheng, Z. X. ;
Li, A. H. ;
Wang, X. L. ;
Dou, S. X. ;
Ozawa, K. ;
Kimura, H. ;
Zhang, S. J. ;
Shrout, T. R. .
JOURNAL OF APPLIED PHYSICS, 2008, 103 (07)
[5]   BI1-XRXFEO3 (R = RARE-EARTH) - A FAMILY OF NOVEL MAGNETOELECTRICS [J].
GABBASOVA, ZV ;
KUZMIN, MD ;
ZVEZDIN, AK ;
DUBENKO, IS ;
MURASHOV, VA ;
RAKOV, DN ;
KRYNETSKY, IB .
PHYSICS LETTERS A, 1991, 158 (09) :491-498
[6]   Low-temperature synthesis of nanosized bismuth ferrite by soft chemical route [J].
Ghosh, S ;
Dasgupta, S ;
Sen, A ;
Maiti, HS .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 2005, 88 (05) :1349-1352
[7]  
ISMILZADE JG, 1971, PHYS STATUS SOLIDI B, V46, pK39
[8]   Magnetic control of ferroelectric polarization [J].
Kimura, T ;
Goto, T ;
Shintani, H ;
Ishizaka, K ;
Arima, T ;
Tokura, Y .
NATURE, 2003, 426 (6962) :55-58
[9]   Ferroelectricity in a pure BiFeO3 ceramic [J].
Kumar, MM ;
Palkar, VR ;
Srinivas, K ;
Suryanarayana, SV .
APPLIED PHYSICS LETTERS, 2000, 76 (19) :2764-2766
[10]   Epitaxially grown la-modified BiFeO3 magnetoferroelectric thin films -: art. no. 222903 [J].
Lee, D ;
Kim, MG ;
Ryu, S ;
Jang, HM ;
Lee, SG .
APPLIED PHYSICS LETTERS, 2005, 86 (22) :1-3