Cu(i)-Catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition reaction

被引：12
|
作者：
Zhang, Changyuan [1 ]
Chen, Lianfen [1 ]
Chen, Kai [1 ]
Wang, Chuntao [1 ]
Xu, Zurong [1 ]
Jiang, Huanfeng [1 ]
Zhu, Shifa [1 ]
机构：
[1] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, Guangzhou 510640, Guangdong, Peoples R China
来源：
ORGANIC CHEMISTRY FRONTIERS | 2018年 / 5卷 / 16期
基金：
中国博士后科学基金;
关键词：
ANTI-MARKOVNIKOV ADDITION; CARBOXYLIC-ACIDS; TERMINAL ALKYNES; RUTHENIUM COMPLEXES; RAPID ACCESS; CATALYSIS; ETHERS; REARRANGEMENT; CYCLIZATION; CARBENES;
D O I：
10.1039/c8qo00664d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient Cu(i)-catalyzed stereoselective synthesis of trisubstituted Z-enol esters via interrupting the 1,3-O-transposition process is reported. This method provided a convenient approach to highly functionalized Z-enol esters with mild reaction conditions and wide substrate scope.
引用
收藏
页码：2510 / 2514
页数：5
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