BODIPY photocatalyzed oxidation of thioanisole under visible light

被引：87

作者：

Li, Wenliang ^{[1
,2
]}

Xie, Zhigang ^{[1
]}

Jing, Xiabin ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China

[2] Chinese Acad Sci, Grad Sch, Beijing 100049, Peoples R China

来源：

CATALYSIS COMMUNICATIONS | 2011年 / 16卷 / 01期

基金：

中国国家自然科学基金;

关键词：

Photocatalysis; Bodipy; Thioanisole; Photo-oxidation; PHOTOREDOX CATALYSIS; SINGLET OXYGEN; CHEMISTRY; INTERMEDIATE; SULFOXIDES; EFFICIENT; DYE; CO2;

D O I：

10.1016/j.catcom.2011.09.007

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

4,4-Difluoro-4-bora-3a,4a-diaza-s-indacene (BODIPY) dyes are organic dyes which have excellent thermal and photochemical stability, high fluorescence quantum yield and good solubility. Four BODIPY dyes were made and used to investigate the oxidation of thioanisole under visible light. BODIPY dyes were shown to be highly active photocatalysts which are comparable to the metal complex, like Ru(bpy)(3)(2+). This work highlights the potential of using BODIPY as photocatalysts for a number of important organic transformations. (C) 2011 Elsevier B.V. All rights reserved.

引用

页码：94 / 97

页数：4

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