Li+ ions diffusion coefficient in V2O5:MoO3 Sol-Gel films

被引：14

作者：

Cholant, C. M. ^{[1
]}

Azevedo, C. F. ^{[2
]}

Caldeira, I. ^{[1
]}

Balboni, R. D. C. ^{[1
]}

Moura, E. A. ^{[3
]}

Westphal, T. M. ^{[1
]}

Pawlicka, A. ^{[4
]}

Berton, M. A. C. ^{[5
]}

Gomez, J. A. ^{[6
]}

Avellaneda, C. O. ^{[1
]}

机构：

[1] Univ Fed Pelotas, Ctr Desenvolvimento Tecnol, Rua Gomes Carneiro 1, BR-96010610 Pelotas, RS, Brazil

[2] Univ Fed Pelotas, Ctr Ciencias Quim Farmaceut & Alimentos CCQFA, Pelotas, RS, Brazil

[3] Univ Fed Parana UFPR, Dept Fis, Ctr Politecn, Curitiba, Parana, Brazil

[4] IQSC USP, Sao Carlos, SP, Brazil

[5] Inst SENAI Inovacao Eletroquim, Curitiba, Parana, Brazil

[6] Univ Fed Pelotas, Inst Fis & Matemat, Pelotas, RS, Brazil

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 2017年 / 655卷 / 01期

关键词：

Chemical diffusion coefficient; cyclic voltammetry; potentiostatic intermittent titration technique; V2O5:MoO3 thin film; THIN-FILMS; OPTICAL-PROPERTIES; LITHIUM DIFFUSION; CATHODE MATERIAL; INTERCALATION; OXIDES; MOO3; PERFORMANCE; BEHAVIOR; GROWTH;

D O I：

10.1080/15421406.2017.1360712

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Present work shows results of Li+ ions insertion and extraction from vanadium pentoxide doped with 5 mol% of molybdenum trioxide (V2O5:MoO3) thin films. The characterizations were performed by cyclic voltammetry (CV), potentiostatic intermittent titration technique (PITT), and electrochemical impedance spectroscopy (EIS). The obtained results revealed Li+ diffusional behavior for anodic and cathodic processes, and it was found that Li+ diffusion coefficient (D) values obtained from CV, PITT, and EIS varied from 10(-10) to 10(-12) cm(2) s(-1). Finally, a diffusion of Li+ process was modeled by solving Fick equation with constant D in plane sheet geometry.

引用

页码：61 / 70

页数：10

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