A Process for the Synthesis of Formic Acid by CO2 Hydrogenation: Thermodynamic Aspects and the Role of CO

被引：260
|
作者：
Schaub, Thomas [1 ]
Paciello, Rocco A. [1 ]
机构：
[1] BASF SE, GCB H M313, D-67056 Ludwigshafen, Germany
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 32期
关键词：
carbon dioxide; formic acid; reaction mechanisms; ruthenium; thermodynamics; CARBON-DIOXIDE HYDROGENATION; RUTHENIUM TRIMETHYLPHOSPHINE COMPLEXES; HOMOGENEOUS HYDROGENATION; CATALYZED HYDROGENATION; RUTHENIUM(II)-CATALYZED HYDROGENATION; DIHYDRIDE; PRESSURE; H-2;
D O I：
10.1002/anie.201101292
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Alcohol and CO: A new process for hydrogenating CO2 to formic acid has been developed. Calorimetric studies were carried out to clarify the role of the alcohol solvent in the catalytic cycle. CO2 hydrogenation is only thermodynamically feasible in the presence of hydrogen-bonding solvents. NMR spectroscopy indicates that catalytically active monocarbonyl complexes are formed when highly basic alkyl phosphine complexes are used as catalysts. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：7278 / 7282
页数：5
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