Syntheses and characterization of dinuclear cadmium(II) diimine complexes with bridging functionalized thiolate ligands

被引：19
作者：
Anjali, KS
Pui, YL
Yam, VWW
Vittal, JJ
机构：
[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China
[2] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
来源：
INORGANICA CHIMICA ACTA | 2001年 / 319卷 / 1-2期
关键词：
thiolate complexes; cadmium complexes; crystal structures; luminescent;
D O I：
10.1016/S0020-1693(01)00438-8
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A series of cationic dinuclear cadmium (II) diimine complexes with bridging functionalized thiolates have been prepared and characterized. The crystal structures of [(bpy)(4)Cd-2(mu -SC6H5)(2)] (ClO4)(2) (1) and [(bpy)(4)Cd-2(mu -SC6H4NH2-4)(2)] (ClO4)(2) (2) have been determined. The photophysical and electrochemical properties of these complexes have also been reported. (C) 2001 Elsevier Science B.V. All rights reserved.
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收藏
页码：57 / 62
页数：6
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