Reactions of unsaturated azides;: Part 22:: The alkyne azide click chemistry as a synthetic tool for the generation of cage-like triazole compounds

被引：9

作者：

Banert, Klaus ^{[1
]}

Wutke, Jens ^{[1
]}

Rueffer, Tobias ^{[1
]}

Lang, Heinrich ^{[1
]}

机构：

[1] Tech Univ Chemnitz, Inst Chem, D-09111 Chemnitz, Germany

来源：

SYNTHESIS-STUTTGART | 2008年 / 16期

关键词：

triazoles; cycloadditions; azides; alkynes; click chemistry;

D O I：

10.1055/s-2008-1078602

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The applicability of the copper(I )-catalyzed click reaction of terminal trialkynes with triazides to the synthesis of cage-like triazole Compounds was determined. A number of starting materials were prepared and several monotriazoles as well as macrocyclic bistriazoles were obtained from the triazide trialkyne reaction. Finally, a tristriazole macrobicyclic compound was synthesized from the previously formed triazole precursors.

引用

页码：2603 / 2609

页数：7

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