Zirconium-pillared montmorillonite and their application in supported palladium catalysts for volatile organic compounds purification

被引：20

作者：

Chen, Min ^{[1
]}

Qi, Lingyan ^{[1
]}

Fan, Liping ^{[1
]}

Zhou, Renxian ^{[1
]}

Zheng, Xiaoming ^{[1
]}

机构：

[1] Zhejiang Univ, Inst Catalysis, Hangzhou, Zhejiang, Peoples R China

来源：

MATERIALS LETTERS | 2008年 / 62卷 / 21-22期

基金：

中国国家自然科学基金;

关键词：

zirconium pillared montmorillonite; rare earth oxides; volatile organic compounds purification;

D O I：

10.1016/j.matlet.2008.04.017

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A novel palladium supported on cerium, lanthanum, praseodymium and zirconium-pillared montmorillonite (MMT) catalysts are prepared and for the catalytic combustion of toluene, acetone and ethyl acetate. The order of catalytic activity is consistent with the different support: La-Zr/MMT approximate to Ce-Zr/MMT > Pr-Zr/MMT. X-ray diffraction (XRD) experiment revealed that the basal spacing of MMT enhanced from 0.97 nm to 1.73 nm after Zr-pillared treatment. After doping of Ce, La and Pr, the interlayer spacing increased to 1.94, 2.02 and 1.85 nm on Ce-Zr/MMT, La-Zr/MMT and Pr-Zr/MMT support. N-2 adsorption-desorption method and scanning electron microscopy (SEM) helped to understand the catalytic performance of these palladium supported and rare earth oxides doped MMT catalysts. (c) 2008 Elsevier B.V. All rights reserved.

引用

页码：3646 / 3648

页数：3

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