Photochemical synthesis of TEMPO-capped initiators for ''living'' free radical polymerization

被引：87

作者：

Connolly, TJ ^{[1
]}

Baldovi, MV ^{[1
]}

Mohtat, N ^{[1
]}

Scaiano, JC ^{[1
]}

机构：

[1] UNIV OTTAWA,DEPT CHEM,OTTAWA,ON K1N 6N5,CANADA

来源：

TETRAHEDRON LETTERS | 1996年 / 37卷 / 28期

关键词：

D O I：

10.1016/0040-4039(96)00986-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two photochemical routes to stoichiometric initiators used in living free radical polymerizations are presented. These routes offer the advantages of higher yields and allow for the preparation of initiators not accessible using current methodology. All initiators gave detectable carbon centered radicals (laser flash pbotolysis) and promoted the polymerization of styrene. Copyright (C) 1996 Elsevier Science Ltd

引用

页码：4919 / 4922

页数：4

共 17 条

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