Rhodium(I), rhodium(III) and iridium(III) carbaporphyrins

被引：23
作者：
Adiraju, Venkata A. K. [1 ]
Ferrence, Gregory M. [1 ]
Lash, Timothy D. [1 ]
机构：
[1] Illinois State Univ, Dept Chem, Normal, IL 61790 USA
来源：
DALTON TRANSACTIONS | 2016年 / 45卷 / 35期
基金：
美国国家科学基金会;
关键词：
N-CONFUSED PORPHYRIN; STRUCTURAL-CHARACTERIZATION; ORGANOMETALLIC COMPLEXES; P-BENZIPORPHYRIN; CARBON-ATOM; AZULIPORPHYRINS; CHEMISTRY; BENZOCARBAPORPHYRINS; PALLADIUM(II); CONTRACTION;
D O I：
10.1039/c6dt03093a
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Treatment of a benzocarbaporphyrin with [Rh(CO)(2)Cl](2) in refluxing dichloromethane gave a rhodium(I) dicarbonyl complex, and further reaction in refluxing pyridine afforded an organometallic rhodium(III) derivative. The carbaporphyrin also reacted with [Ir(COD)Cl](2) and pyridine in refluxing p-xylene to generate a related iridium(III) compound. These novel metalated porphyrinoids retained strongly diatropic characteristics and were fully characterized by XRD.
引用
收藏
页码：13691 / 13694
页数：4
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